Distinct nanostructures from a molecular shuttle: effects of shuttling movement on nanostructural morphologies
文献类型：期刊论文
| 作者 | Zhou, Weidong1,2; Xu, Jialiang1,2; Zheng, Haiyan1,2; Yin, Xiaodong1,2; Zuo, Zicheng1,2; Liu, Huibiao1,2; Li, Yuliang1,2 |
| 刊名 | Advanced functional materials
 |
| 出版日期 | 2009-01-09 |
| 卷号 | 19期号:1页码:141-149 |
| ISSN号 | 1616-301X |
| DOI | 10.1002/adfm.200801149 |
| 通讯作者 | Zhou, weidong() |
| 英文摘要 | A solvent driven molecular shuttle that contains a tcbd chromophore and in which the macrocycle can be positioned close to or far from the tcbd unit with a change of solvent is prepared. several distinct nanostructures are obtained by control of the shuttling movement of the macrocycle: i) in a mixed solvent of chcl(3)/n-c(6)h(14) (1/1, v/v), the macrocycle locates at the peptide station, and interlaced nanofibers form as a result of the extended intermolecular dipole-dipole interactions of the tcbd units; ii) in a solvent of dimethyl sulfoxide, the macrocycle moves along the long alkyl-chain, and worm-like nanoparticles form because the macrocycle obstructs the intermolecular dipole-dipole interactions of the tcbd units. this system c firms that the molecular aggregation behaviors can be controlled by the shuttling movement of the macrocycle. exploitation of the molecular shuttle to control the molecular aggregation behaviors will provide greater understanding in the field of molecular shuttle applications. |
| WOS关键词 | COIL BLOCK-COPOLYMERS ; LINEAR ROTAXANE DIMER ; TRANSLATIONAL MOTION ; VESICLES ; EMISSION ; NANOCAPSULES ; CONTRACTION ; NANOVALVES ; NANOFIBERS ; VERSATILE |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS类目 | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| 语种 | 英语 |
| WOS记录号 | WOS:000262584800014 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2401941 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhou, Weidong |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, BNLMS, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Weidong,Xu, Jialiang,Zheng, Haiyan,et al. Distinct nanostructures from a molecular shuttle: effects of shuttling movement on nanostructural morphologies[J]. Advanced functional materials,2009,19(1):141-149. |
| APA | Zhou, Weidong.,Xu, Jialiang.,Zheng, Haiyan.,Yin, Xiaodong.,Zuo, Zicheng.,...&Li, Yuliang.(2009).Distinct nanostructures from a molecular shuttle: effects of shuttling movement on nanostructural morphologies.Advanced functional materials,19(1),141-149. |
| MLA | Zhou, Weidong,et al."Distinct nanostructures from a molecular shuttle: effects of shuttling movement on nanostructural morphologies".Advanced functional materials 19.1(2009):141-149. |
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来源：中国科学院大学
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