中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
An approach for the surface functionalized gold nanoparticles with ph-responsive polymer by combination of raft and click chemistry

文献类型:期刊论文

作者Zhang, Tao1,2; Wu, Yuanpeng1; Pan, Xuemei1; Zheng, Zhaohui1; Ding, Xiaobin1; Peng, Yuxing1
刊名European polymer journal
出版日期2009-06-01
卷号45期号:6页码:1625-1633
ISSN号0014-3057
关键词Click chemistry Gold nanoparticles Ph responsive Raft
DOI10.1016/j.eurpolymj.2009.03.016
通讯作者Ding, xiaobin(xbding@cioc.ac.cn)
英文摘要In this report, we demonstrated a novel efficient post-modification route for preparation of smart hybrid gold nanoparticles with poly(4-vinylpyridine) (p4vp) based on raft and click chemistry. a new azide terminated ligand was first synthesized to modify gold nanoparticles by ligand exchange reaction, and then click reaction was used to graft alkyne terminated p4vp which was prepared by raft onto the surface of gold nanoparticles. the functionalized hybrid gold nanoparticles were characterized by tem, ftir, and xps etc. the results indicated that the p4vp was successfully grafted onto the surface of gold nanoparticles by click reaction. the surface grafting density was calculated to be about 6 chains/nm(2). in addition, the hybrid gold nanoparticles showed a ph responsive phenomenon as the ph value changed around 5. crown copyright (c) 2009 published by elsevier ltd. all rights reserved.
WOS关键词TRANSFER RADICAL POLYMERIZATION ; 4-VINYLPYRIDINE ; CYCLOADDITION ; SCIENCE ; COPOLYMERS ; SYSTEMS ; ROUTE ; ATRP
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000266857200001
URI标识http://www.irgrid.ac.cn/handle/1471x/2402847
专题中国科学院大学
通讯作者Ding, Xiaobin
作者单位1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100081, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Tao,Wu, Yuanpeng,Pan, Xuemei,et al. An approach for the surface functionalized gold nanoparticles with ph-responsive polymer by combination of raft and click chemistry[J]. European polymer journal,2009,45(6):1625-1633.
APA Zhang, Tao,Wu, Yuanpeng,Pan, Xuemei,Zheng, Zhaohui,Ding, Xiaobin,&Peng, Yuxing.(2009).An approach for the surface functionalized gold nanoparticles with ph-responsive polymer by combination of raft and click chemistry.European polymer journal,45(6),1625-1633.
MLA Zhang, Tao,et al."An approach for the surface functionalized gold nanoparticles with ph-responsive polymer by combination of raft and click chemistry".European polymer journal 45.6(2009):1625-1633.

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