Dithiolane linked thiorhodamine dimer for hg2+ recognition in living cells
文献类型：期刊论文
| 作者 | Liu, Weimin2; Xu, Liwei1,2; Zhang, Hongyan2; You, Juanjuan2,3; Zhang, Xiaoling1; Sheng, Ruilong2; Li, Huaping4,5; Wu, Shikang2; Wang, Pengfei2 |
| 刊名 | Organic & biomolecular chemistry
 |
| 出版日期 | 2009 |
| 卷号 | 7期号:4页码:660-664 |
| ISSN号 | 1477-0520 |
| DOI | 10.1039/b815956d |
| 通讯作者 | Zhang, xiaoling(zhangxl@bit.edu.cn) |
| 英文摘要 | Thiorhodamine-based chemodosimeter a, a disulfide linked dimer, was designed for hg2+ recognition by virtue of the strong affinity of mercury for sulfur. spectroscopic results reveal that chemodosimeter a exhibits real-time responses, and high sensitivity and selectivity for hg2+ in comparison to other cations. these properties are mechanistically ascribed to the transfer from rhodamine spirolactam to the thiazoline-derived open-ring rhodamine via hg2+ induced desulfurization. the in vitro recognition of hg2+ in living cells pretreated with a was examined, showing that the concentration of hg2+ that could be imaged reaches the safety limit for human beings. |
| WOS关键词 | SELECTIVE FLUORESCENT CHEMOSENSOR ; MERR FAMILY PROTEINS ; MERCURY IONS ; TURN-ON ; HG2+-SELECTIVE CHEMODOSIMETER ; AQUEOUS-SOLUTIONS ; SENSOR ; WATER ; DESIGN ; HG(II) |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000263113100009 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2403081 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhang, Xiaoling |
| 作者单位 | 1.Beijing Inst Technol, Sch Sci, Dept Chem, Beijing 100081, Peoples R China 2.Chinese Acad Sci, Tech Inst Phys & Chem, Lab Organ Optoelect Funct Mat & Mol Engn, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China 4.Univ Calif Santa Barbara, Dept Mat, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA 5.Univ Calif Santa Barbara, Dept Chem & Biochem, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA |
| 推荐引用方式 GB/T 7714 | Liu, Weimin,Xu, Liwei,Zhang, Hongyan,et al. Dithiolane linked thiorhodamine dimer for hg2+ recognition in living cells[J]. Organic & biomolecular chemistry,2009,7(4):660-664. |
| APA | Liu, Weimin.,Xu, Liwei.,Zhang, Hongyan.,You, Juanjuan.,Zhang, Xiaoling.,...&Wang, Pengfei.(2009).Dithiolane linked thiorhodamine dimer for hg2+ recognition in living cells.Organic & biomolecular chemistry,7(4),660-664. |
| MLA | Liu, Weimin,et al."Dithiolane linked thiorhodamine dimer for hg2+ recognition in living cells".Organic & biomolecular chemistry 7.4(2009):660-664. |
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来源：中国科学院大学
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