Infrared, raman and xps spectroscopic studies of bi2o3-b2o3-ga2o3 glasses
文献类型：期刊论文
| 作者 | Fan, Huiyan1,2; Wang, Guonian1; Hu, Lili1 |
| 刊名 | Solid state sciences
 |
| 出版日期 | 2009-12-01 |
| 卷号 | 11期号:12页码:2065-2070 |
| 关键词 | Ir and raman spectroscopy Xps Glass structure Bismuthate glasses |
| ISSN号 | 1293-2558 |
| DOI | 10.1016/j.solidstatesciences.2009.09.007 |
| 通讯作者 | Fan, huiyan(fanhuiyan276622@hotmail.com) |
| 英文摘要 | Glasses with compositions 60bi(2)o(3)-(40-x)b2o3-xga(2)o(3) (x = 5, 10, 15, 20 mol%) are prepared by conventional melting method. the thermal properties are investigated by differential thermal analysis (dta) and the structures of the glasses were probed by infrared, raman and x-ray photoelectron spectroscopy (xps). the results show that density, refractive index and optical basicity increase with the increase of ga2o3. the glass transition temperature (t-g), the onset crystallization temperature (t-x), delta t (t-x-t-g) decrease with the content of ga2o3. the cut-off edges in ultraviolet and infrared shift to longer wavelength with the increase of ga2o3. on the other hand, the addition of ga2o3 causes a progressive coordination number change of the boron atom from 3 to 4. xps result indicates both bi5+ and bi3+ exist in 5 mol% ga2o3 content, while bi5+ amounts decrease with the increase of ga2o3 contents. the glass is mainly composed of [bio6], [bo3], [bo4] and [gao4] polyhedra. glasses are supposed to have layer structure. [bo3] triangle and [bo4] tetrahedra may be located between the [gao4] tetrahedral and [bio6] octahedra to prevent crystallization and to compensate electric charge. (c) 2009 elsevier masson sas. all rights reserved. |
| WOS关键词 | OPTICAL BASICITY ; ELECTRONIC POLARIZABILITY ; BORATE GLASSES ; GALLATE GLASSES ; OXIDE GLASSES ; BISMUTH OXIDE ; SYSTEM ; SPECTRA ; BI2O3 ; ALKALI |
| WOS研究方向 | Chemistry ; Physics |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Physical ; Physics, Condensed Matter |
| 语种 | 英语 |
| WOS记录号 | WOS:000273067400007 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2404594 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Fan, Huiyan |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Key Lab Mat High Power Laser, Shanghai 201800, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Huiyan,Wang, Guonian,Hu, Lili. Infrared, raman and xps spectroscopic studies of bi2o3-b2o3-ga2o3 glasses[J]. Solid state sciences,2009,11(12):2065-2070. |
| APA | Fan, Huiyan,Wang, Guonian,&Hu, Lili.(2009).Infrared, raman and xps spectroscopic studies of bi2o3-b2o3-ga2o3 glasses.Solid state sciences,11(12),2065-2070. |
| MLA | Fan, Huiyan,et al."Infrared, raman and xps spectroscopic studies of bi2o3-b2o3-ga2o3 glasses".Solid state sciences 11.12(2009):2065-2070. |
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来源：中国科学院大学
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