A highly efficient chiral-bridged diphosphine ligand modified cationic palladium(ii) catalyst system for asymmetric alternating copolymerization of propene and carbon monoxide
文献类型：期刊论文
| 作者 | Cui, Yuming1,2; Wang, Lailai1; Kwong, Fuk Yee3,4; Tse, Man Kin5; Chan, Albert S. C.3,4 |
| 刊名 | Synlett
 |
| 出版日期 | 2009-10-01 |
| 期号 | 16页码:2696-2700 |
| 关键词 | Palladium Chiral-bridged biphenyl diphosphine Propene and co Asymmetric alternating copolymerization Chiral polyketone |
| ISSN号 | 0936-5214 |
| DOI | 10.1055/s-0029-1217957 |
| 通讯作者 | Wang, lailai(wll@lzb.ac.cn) |
| 英文摘要 | A highly efficient chiral-bridged biphenyl diphosphine ligand [(r(ax))-bup] modified cationic palladium(ii) catalyst system for the synthesis of optically active polyketone by stereoselective alternating copolymerization of propene and carbon monoxide is reported for the first time. the results show that [pd(mecn)(4)][otf](2) is an excellent catalyst precursor in a mixed solvent of meno(2)-meoh. the highest catalytic activity was found to be 221 g polymer/(g pd.h). a chiral polyketone with molecular weight m(n) = 2.9 x 10(4), polydispersity = 1.4, and molar optical rotation = +37 degrees was afforded under optimized reaction conditions. |
| WOS关键词 | MECHANISTIC ASPECTS ; ALPHA-OLEFINS ; MACROMOLECULAR STEREOCHEMISTRY ; COMPLEXES ; ETHENE ; POLYISOCYANATES ; POLYMERIZATION ; HYDROGENATION ; SOLVENT |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000273766700031 |
| 出版者 | GEORG THIEME VERLAG KG |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2404612 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang, Lailai |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China 3.Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China 4.Hong Kong Polytech Univ, Open Lab Chirotechnol, Inst Mol Technol Drug Discovery & Synth, Hong Kong, Hong Kong, Peoples R China 5.Univ Rostock, Leibniz Inst Catalysis eV, D-18059 Rostock, Germany |
| 推荐引用方式 GB/T 7714 | Cui, Yuming,Wang, Lailai,Kwong, Fuk Yee,et al. A highly efficient chiral-bridged diphosphine ligand modified cationic palladium(ii) catalyst system for asymmetric alternating copolymerization of propene and carbon monoxide[J]. Synlett,2009(16):2696-2700. |
| APA | Cui, Yuming,Wang, Lailai,Kwong, Fuk Yee,Tse, Man Kin,&Chan, Albert S. C..(2009).A highly efficient chiral-bridged diphosphine ligand modified cationic palladium(ii) catalyst system for asymmetric alternating copolymerization of propene and carbon monoxide.Synlett(16),2696-2700. |
| MLA | Cui, Yuming,et al."A highly efficient chiral-bridged diphosphine ligand modified cationic palladium(ii) catalyst system for asymmetric alternating copolymerization of propene and carbon monoxide".Synlett .16(2009):2696-2700. |
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来源：中国科学院大学
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