A novel approach to molecular recognition surface of magnetic nanoparticles based on host-guest effect
文献类型:期刊论文
作者 | Wu, Yuanpeng1,3; Zuo, Fang2; Zheng, Zhaohui1; Ding, Xiaobin1; Peng, Yuxing1 |
刊名 | Nanoscale research letters
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出版日期 | 2009-07-01 |
卷号 | 4期号:7页码:738-747 |
关键词 | Beta-cyclodextrin Magnetic nanoparticles Molecular recognition Dopamine |
ISSN号 | 1931-7573 |
DOI | 10.1007/s11671-009-9314-x |
通讯作者 | Ding, xiaobin(xbding@cioc.ac.cn) |
英文摘要 | A novel route has been developed to prepared beta-cyclodextrin (beta-cd) functionalized magnetic nanoparticles (mnps). the mnps were first modified with monotosyl-poly(ethylene glycol) (peg) silane and then tosyl units were displaced by amino-beta-cd through the nucleophilic substitution reaction. the monotosyl-peg silane was synthesized by modifying a peg diol to form the corresponding monotosyl-peg, followed by a reaction with 3-isocyanatopropyltriethoxysilane (ipts). the success of the synthesis of the monotosyl-peg silane was confirmed with (1)h nmr and fourier transform infrared (ftir) spectroscopy. the analysis of ftir spectroscopy and x-ray photoelectron spectroscopy (xps) confirmed the immobilization of beta-cd onto mnps. transmission electron microscopy (tem) indicated that the beta-cd functionalized mnps were mostly present as individual nonclustered units in water. the number of beta-cd molecules immobilized on each mnp was about 240 according to the thermogravimetric analysis (tga) results. the as-prepared beta-cd functionalized mnps were used to detect dopamine with the assistance of a magnet. |
WOS关键词 | POLYCYCLIC AROMATIC-HYDROCARBONS ; THIOLATED BETA-CYCLODEXTRIN ; MODIFIED GOLD NANOPARTICLES ; ENHANCED RAMAN-SCATTERING ; PALLADIUM NANOPARTICLES ; QUANTUM DOTS ; SELECTIVE DETECTION ; LUMINESCENT PROBES ; AG NANOPARTICLES ; ASCORBIC-ACID |
WOS研究方向 | Science & Technology - Other Topics ; Materials Science ; Physics |
WOS类目 | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied |
语种 | 英语 |
WOS记录号 | WOS:000266584900023 |
出版者 | SPRINGER |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2404739 |
专题 | 中国科学院大学 |
通讯作者 | Ding, Xiaobin |
作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 2.Univ Elect Sci & Technol China, Res Branch Funct Mat, State Key Lab Elect Films & Integrated Devices, Chengdu 610054, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Wu, Yuanpeng,Zuo, Fang,Zheng, Zhaohui,et al. A novel approach to molecular recognition surface of magnetic nanoparticles based on host-guest effect[J]. Nanoscale research letters,2009,4(7):738-747. |
APA | Wu, Yuanpeng,Zuo, Fang,Zheng, Zhaohui,Ding, Xiaobin,&Peng, Yuxing.(2009).A novel approach to molecular recognition surface of magnetic nanoparticles based on host-guest effect.Nanoscale research letters,4(7),738-747. |
MLA | Wu, Yuanpeng,et al."A novel approach to molecular recognition surface of magnetic nanoparticles based on host-guest effect".Nanoscale research letters 4.7(2009):738-747. |
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来源:中国科学院大学
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