A comparison of crystallite and pore structures in different polyacrylonitrile-based carbon fibers
文献类型:期刊论文
作者 | Wen Yue-fang1,2; Guo Jian-qiang2,3; Gao Zhong-min4; Li Xiang-shan4; Cao Xia5; Yang Yong-gang1; Liu Lang1 |
刊名 | New carbon materials
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出版日期 | 2009-06-01 |
卷号 | 24期号:2页码:153-158 |
关键词 | Polyacrylonitrile-based carbon fiber Waxd Saxs Crystallite Pore |
ISSN号 | 1007-8827 |
通讯作者 | Yang yong-gang(yangyg@sxicc.ac.cn) |
英文摘要 | Home-made polyacrylonitrile-based carbon fiber and the t300b, t700sc and m55jb products of toray were investigated and compared by waxd and saxs. the waxd results show that, the l(c), d(002), l(c)/d(002) and pore content of the home-made carbon fiber were all between that of t300b and t700sc, and its l(a) value was close to that of t700sc. the saxs results suggest that the cylindrical pores with a in value (length of semi-major axis) less than 5 nm were 99.72% in t700sc, and there were no pores with in value around 30 nm, which was better than that of home-made carbon fiber and t300b. there was a large number of pores with m approximate to 7-15 nm in m55jb, as a result, the strength of m55jb was less than that of t700sc. the pores in t700sc and m55jb had the ratios of in to pore radius larger than that of the home-made carbon fiber. the pore orientation angle of home-made carbon fiber, and toray t300 and t700 carbon fibers are all about 21-22. however, the pore orientation angle of m55jb graphite fiber is 8 degrees, less than that of the others. in order to improve the performance of home-made carbon fiber, efforts should be made to increase the degree of graphitization, to reduce the d(002) and pore content and to increase degree of densification. the number of larger pores should be reduced and eliminated, and the number of smaller pores should be increased from the spinning of the precursor fiber through stabilization and carbonization. |
WOS关键词 | X-RAY-SCATTERING |
WOS研究方向 | Materials Science |
WOS类目 | Materials Science, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000267634200011 |
出版者 | SCIENCE PRESS |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2404783 |
专题 | 中国科学院大学 |
通讯作者 | Yang Yong-gang |
作者单位 | 1.Chinese Acad Sci, Key Lab Carbon Mat, Inst Coal Chem, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China 4.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 5.Beijing Aeronaut Mfg Technol Res Inst, Beijing 100024, Peoples R China |
推荐引用方式 GB/T 7714 | Wen Yue-fang,Guo Jian-qiang,Gao Zhong-min,et al. A comparison of crystallite and pore structures in different polyacrylonitrile-based carbon fibers[J]. New carbon materials,2009,24(2):153-158. |
APA | Wen Yue-fang.,Guo Jian-qiang.,Gao Zhong-min.,Li Xiang-shan.,Cao Xia.,...&Liu Lang.(2009).A comparison of crystallite and pore structures in different polyacrylonitrile-based carbon fibers.New carbon materials,24(2),153-158. |
MLA | Wen Yue-fang,et al."A comparison of crystallite and pore structures in different polyacrylonitrile-based carbon fibers".New carbon materials 24.2(2009):153-158. |
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来源:中国科学院大学
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