Synthesis, structure and redox property of a new tetrathiafulvalene-based macrocyclic compound
文献类型：期刊论文
| 作者 | Lue Haiyan |
| 刊名 | Chinese journal of organic chemistry
 |
| 出版日期 | 2009-02-01 |
| 卷号 | 29期号:2页码:234-238 |
| 关键词 | Tetrathiafulvalene 2,5-bis(chloromethyl)thiophene Macrocyclic compound Crystal structure Redox property |
| ISSN号 | 0253-2786 |
| 通讯作者 | Lue haiyan(haiyanlu@gucas.ac.cn) |
| 英文摘要 | A new macrocyclic compound based on tetrathiafulvalene (ttf) and 2,5-bis(chloromethyl)thiophene was synthesized and structurally characterized by elemental analysis, (1)h nmr spectrum, maldi-tof ms and x-ray single-crystal diffraction analysis. the crystal of compound i belongs to monoclinic space group p2(1)/n with cell parameters a=0.97220(19) nm, b=1.2366(3) nm, c=1.6051(3) nm, beta=95.41(3)degrees, v=1.9211(7) nm(3), z=2, d(c)=1.621 g/cm(3), f(000)=960, mu=1.032 mm(-1), r=0.0333, and wr=0.1000 [i>2 sigma(i)]. moreover, compound 1 displayed two couples of cathodic and anodic peaks in the cyclic voltammogram, and the redox processes are irreversible. |
| WOS关键词 | BEDT-TTF ; CHEMISTRY ; ANIONS ; UNITS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000264232100012 |
| 出版者 | SCIENCE PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2404873 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Lue Haiyan |
| 作者单位 | Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lue Haiyan. Synthesis, structure and redox property of a new tetrathiafulvalene-based macrocyclic compound[J]. Chinese journal of organic chemistry,2009,29(2):234-238. |
| APA | Lue Haiyan.(2009).Synthesis, structure and redox property of a new tetrathiafulvalene-based macrocyclic compound.Chinese journal of organic chemistry,29(2),234-238. |
| MLA | Lue Haiyan."Synthesis, structure and redox property of a new tetrathiafulvalene-based macrocyclic compound".Chinese journal of organic chemistry 29.2(2009):234-238. |
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来源：中国科学院大学
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