Synthesis and crystal structure of a new complex {[(col2)-l-iii]center dot[co-ii(h2o)(6)](0.5)center dot 2.25h(2)o}(4) (h2l = n-(2-hydroxyphenyl)salicylidenimine)
文献类型：期刊论文
| 作者 | Yang Li-Li1,2; Dang Zhen-Hua1,2; Xu Li1 |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2009 |
| 卷号 | 28期号:4页码:493-497 |
| 关键词 | Schiff base N-(2-hydroxyphenyl)salicylidenimine Crystal structure |
| ISSN号 | 0254-5861 |
| 通讯作者 | Xu li(xli@ms.fjirsm.ac.cn) |
| 英文摘要 | The reaction of co(oac)(2)center dot 4h(2)o with the schiff base h2l in a methanol solution affords the red crystals of {[(col2)-l-iii]center dot[co-ii(h2o)(6)](0.5)center dot 2.25h(2)o}(4) 1 (h2l = n-(2-hydroxyphenyl) salicylidenimine). the molecular and crystal structures were determined by single-crystal x-ray diffraction. the crystal is of monoclinic, space group p2(1)/n, c104h114co6n8o37, m-r = 2421.61, a = 10.625(3), b = 16.335(4), c = 15.265(4) angstrom, beta = 102.990(4)degrees, v = 2581.6(11) angstrom(3), z = 1, d-c = 1.558 g/cm(3), mu = 1.034 mm(-1), f(000) = 1252, r 0.0414 and wr = 0.1167 for 5889 reflections. the co(iii) atom is six-coordinated by two nitrogen atoms and four oxygen atoms of two tridentate l ligands. the abundant hydrogen bonding interactions extend the complex into a one-dimensional supra- molecular framework. the uncoordinated water molecules act as space-fillers and consolidate the whole architecture through the hydrogen bonding interactions. |
| WOS关键词 | WEAK HYDROGEN-BONDS ; SCHIFF-BASES ; SUPRAMOLECULAR SYNTHONS ; AROMATIC-HYDROCARBONS ; PERSPECTIVES ; RECOGNITION ; MOLECULES ; CHEMISTRY ; ADDUCTS ; LIGANDS |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000265662800019 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2405168 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xu Li |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang Li-Li,Dang Zhen-Hua,Xu Li. Synthesis and crystal structure of a new complex {[(col2)-l-iii]center dot[co-ii(h2o)(6)](0.5)center dot 2.25h(2)o}(4) (h2l = n-(2-hydroxyphenyl)salicylidenimine)[J]. Chinese journal of structural chemistry,2009,28(4):493-497. |
| APA | Yang Li-Li,Dang Zhen-Hua,&Xu Li.(2009).Synthesis and crystal structure of a new complex {[(col2)-l-iii]center dot[co-ii(h2o)(6)](0.5)center dot 2.25h(2)o}(4) (h2l = n-(2-hydroxyphenyl)salicylidenimine).Chinese journal of structural chemistry,28(4),493-497. |
| MLA | Yang Li-Li,et al."Synthesis and crystal structure of a new complex {[(col2)-l-iii]center dot[co-ii(h2o)(6)](0.5)center dot 2.25h(2)o}(4) (h2l = n-(2-hydroxyphenyl)salicylidenimine)".Chinese journal of structural chemistry 28.4(2009):493-497. |
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来源：中国科学院大学
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