One-pot synthesis of ethylene glycol and its mono-methyl ether from ethylene using al-ts-1 catalyst
文献类型：期刊论文
| 作者 | Li, Hao1,2; Lei, Qian1; Zhang, Xiaoming1; Suo, Jishuan1 |
| 刊名 | Catalysis communications
 |
| 出版日期 | 2009-08-25 |
| 卷号 | 10期号:14页码:1936-1939 |
| 关键词 | Ethylene Ethylene glycol Ethylene glycol mono-methyl ether Epoxidation Bifunctional Al-ts-1 |
| ISSN号 | 1566-7367 |
| DOI | 10.1016/j.catcom.2009.07.004 |
| 通讯作者 | Zhang, xiaoming(xm.zhang@cioc.ac.cn) |
| 英文摘要 | Ethylene glycol (eg) and its mono-methyl ether (mme) were synthesized directly from ethylene and hydrogen peroxide under mild conditions using al-ts-1 as the bifunctional catalyst. the progressive incorporation of al into the framework increased the catalytic capacity of al-ts-1 until a maximum was reached (sio(2)/al(2)o(3) molar ratio: 504), whereas further al incorporation decreased the catalytic activity to even lower values than in ts-1. under the optimum conditions, the conversion and utilization of h(2)o(2) reached 95% and 90%, respectively, while the total concentration of eg and mme reached to above 10 wt%. (c) 2009 elsevier b.v. all rights reserved. |
| WOS关键词 | HYDROGEN-PEROXIDE ; TITANIUM SILICALITE ; MOLECULAR-SIEVES ; AL ; TI ; PROPYLENE ; OXIDATION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000269664200031 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2405194 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhang, Xiaoming |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Hao,Lei, Qian,Zhang, Xiaoming,et al. One-pot synthesis of ethylene glycol and its mono-methyl ether from ethylene using al-ts-1 catalyst[J]. Catalysis communications,2009,10(14):1936-1939. |
| APA | Li, Hao,Lei, Qian,Zhang, Xiaoming,&Suo, Jishuan.(2009).One-pot synthesis of ethylene glycol and its mono-methyl ether from ethylene using al-ts-1 catalyst.Catalysis communications,10(14),1936-1939. |
| MLA | Li, Hao,et al."One-pot synthesis of ethylene glycol and its mono-methyl ether from ethylene using al-ts-1 catalyst".Catalysis communications 10.14(2009):1936-1939. |
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来源：中国科学院大学
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