Sulfamic acid as a cost-effective and recyclable catalyst for beta-amino carbonyl compounds synthesis
文献类型：期刊论文
| 作者 | Luo, Hai-Tang1,2; Kang, Yu-Ru1; Nie, Hong-Yun1,2; Yang, Li-Ming1 |
| 刊名 | Journal of the chinese chemical society
 |
| 出版日期 | 2009-02-01 |
| 卷号 | 56期号:1页码:186-195 |
| 关键词 | Sulfamic acid Beta-amino carbonyl compounds Beta,beta '-diamino diketone compounds Acetophenone Isophthalic aldehyde |
| ISSN号 | 0009-4536 |
| 通讯作者 | Yang, li-ming(limy@lzb.ac.cn) |
| 英文摘要 | Sulfamic acid was used as a catalyst in the synthesis of beta-amino carbonyl compounds from amines, acetophenone and aldehyde. the reaction was carried out at room temperature. high selectivity, mild reaction temperature, cost-effective catalyst, simple product separation and catalyst recycle were notable achievements in the reaction. another feature was that the reaction could be performed on a relatively larger scale to the model reaction (50 times), which also gave good yields. in particular, the first preparation of beta,beta'-diamino diketone derivatives via the direct coupling of amines, acetophenone and isophthalic aldehyde promoted by sulfamic acid has been developed. |
| WOS关键词 | MANNICH-TYPE REACTION ; KETENE SILYL ACETALS ; AROMATIC-ALDEHYDES ; SCHIFF-BASES ; ASYMMETRIC-SYNTHESIS ; LANTHANIDE TRIFLATE ; AQUEOUS-MEDIA ; ENOL ETHERS ; ALDOL-TYPE ; KETONES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000264165300027 |
| 出版者 | CHINESE CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2405367 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yang, Li-Ming |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Ecomat & Green Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Luo, Hai-Tang,Kang, Yu-Ru,Nie, Hong-Yun,et al. Sulfamic acid as a cost-effective and recyclable catalyst for beta-amino carbonyl compounds synthesis[J]. Journal of the chinese chemical society,2009,56(1):186-195. |
| APA | Luo, Hai-Tang,Kang, Yu-Ru,Nie, Hong-Yun,&Yang, Li-Ming.(2009).Sulfamic acid as a cost-effective and recyclable catalyst for beta-amino carbonyl compounds synthesis.Journal of the chinese chemical society,56(1),186-195. |
| MLA | Luo, Hai-Tang,et al."Sulfamic acid as a cost-effective and recyclable catalyst for beta-amino carbonyl compounds synthesis".Journal of the chinese chemical society 56.1(2009):186-195. |
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来源：中国科学院大学
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