Iron carbide promoted k/beta-mo(2)c for higher alcohols synthesis
文献类型：期刊论文
| 作者 | Wang, Ning1,2; Fang, Kegong1; Jiang, Dong1; Li, Debao1; Sun, Yuhan1 |
| 刊名 | Catalysis today
 |
| 出版日期 | 2010-12-22 |
| 卷号 | 158期号:3-4页码:241-245 |
| 关键词 | Iron carbide modified K/beta-mo(2)c Higher alcohols synthesis Syngas |
| ISSN号 | 0920-5861 |
| DOI | 10.1016/j.cattod.2010.03.079 |
| 通讯作者 | Sun, yuhan(yhsun@sxicc.ac.cn) |
| 英文摘要 | Iron carbide promoted k/beta-mo(2)c catalysts were prepared and tested for higher alcohols synthesis. the results revealed that beta-mo(2)c produced mainly hydrocarbons, but the addition of potassium resulted in a remarkable selectivity shift from hydrocarbons to alcohols and then a higher selectivity to c(2)(+)oh over beta-mo(2)c. moreover, it was found that iron carbide further enhanced the selectivity of higher alcohols, showing the optimum at 1/6 of fe/mo molar ratio. the corresponding characterization suggested that there might be a synergistic effect of iron carbide and k/beta-mo(2)c, i.e. the formation of "k-fe-mo-c" species which favored the alcohols synthesis. (c) 2010 elsevier b.v. all rights reserved. |
| WOS关键词 | FISCHER-TROPSCH SYNTHESIS ; CARBON-MONOXIDE HYDROGENATION ; SYNTHESIS GAS ; MIXED ALCOHOLS ; SYNTHESIS CATALYSTS ; MOLYBDENUM ; SPECTROSCOPY ; CONVERSION ; REDUCTION ; SYNGAS |
| WOS研究方向 | Chemistry ; Engineering |
| WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000284583300009 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2406036 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Sun, Yuhan |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Coal Convers, Shanxi Inst Coal Chem, Taiyuan 030001, Shanxi, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Ning,Fang, Kegong,Jiang, Dong,et al. Iron carbide promoted k/beta-mo(2)c for higher alcohols synthesis[J]. Catalysis today,2010,158(3-4):241-245. |
| APA | Wang, Ning,Fang, Kegong,Jiang, Dong,Li, Debao,&Sun, Yuhan.(2010).Iron carbide promoted k/beta-mo(2)c for higher alcohols synthesis.Catalysis today,158(3-4),241-245. |
| MLA | Wang, Ning,et al."Iron carbide promoted k/beta-mo(2)c for higher alcohols synthesis".Catalysis today 158.3-4(2010):241-245. |
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来源：中国科学院大学
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