Sulfate binding in zinc(ii) complexes of a monopyridylurea ligand n-(1-naphthyl)-n '-(3-pyridyl)urea
文献类型：期刊论文
| 作者 | Huang, Xiaojuan1; Yang, Zaiwen1,2; Yang, Xiao-Juan1; Zhao, Qilong1,2; Xia, Yana1,2; Wu, Biao1 |
| 刊名 | Inorganic chemistry communications
 |
| 出版日期 | 2010-09-01 |
| 卷号 | 13期号:9页码:1103-1107 |
| 关键词 | Sulfate binding N-(1-naphthyl)-n '-(3-pyridyl)urea Hydrogen-bonded frameworks Fluorescence |
| ISSN号 | 1387-7003 |
| DOI | 10.1016/j.inoche.2010.06.037 |
| 通讯作者 | Wu, biao(wubiao@lzb.ac.cn) |
| 英文摘要 | Two zinc(ii) complexes of a urea-functionalized pyridyl ligand, [zn(so(4))l(3)]center dot ch(3)oh (1) and {[zn((mu(2)-so(4))l(2)]center dot 0.5ch(3)oh)(n) (2) (l = n-(1-naphthyl)-n'-(3-pyridyl)urea), have been synthesized by the reaction of l with znso(4)center dot 7h(2)o under different conditions. complex 1 is a hydrogen-bonded 2d grid structure in which the sulfate anion not only coordinates to the zn(ii) ion as a monodentate ligand but also forms multiple hydrogen bonds with the urea groups of adjacent molecules. in complex 2 the sulfate ion serves as a mu(2)-bridging ligand, connecting the zn(ii) ions to form an infinite 1d organic-inorganic hybrid framework. meanwhile, the sulfate anion is also bound by neighboring ligands through hydrogen bonds between urea groups and the non-coordinated oxygen atoms. the solid-state emission spectra of 1 and 2 show a red shift of the fluorescence emission of ligand l. (c) 2010 elsevier b.v. all rights reserved. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; HYDROGEN-BONDING GROUPS ; OXO-ANION BINDING ; COORDINATION POLYMERS ; SELECTIVE CRYSTALLIZATION ; SUPRAMOLECULAR STRUCTURES ; CRYSTAL-STRUCTURES ; DIPYRIDYL LIGANDS ; UREA ; ZN(II) |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000281011900026 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2406058 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Biao |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Xiaojuan,Yang, Zaiwen,Yang, Xiao-Juan,et al. Sulfate binding in zinc(ii) complexes of a monopyridylurea ligand n-(1-naphthyl)-n '-(3-pyridyl)urea[J]. Inorganic chemistry communications,2010,13(9):1103-1107. |
| APA | Huang, Xiaojuan,Yang, Zaiwen,Yang, Xiao-Juan,Zhao, Qilong,Xia, Yana,&Wu, Biao.(2010).Sulfate binding in zinc(ii) complexes of a monopyridylurea ligand n-(1-naphthyl)-n '-(3-pyridyl)urea.Inorganic chemistry communications,13(9),1103-1107. |
| MLA | Huang, Xiaojuan,et al."Sulfate binding in zinc(ii) complexes of a monopyridylurea ligand n-(1-naphthyl)-n '-(3-pyridyl)urea".Inorganic chemistry communications 13.9(2010):1103-1107. |
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来源：中国科学院大学
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