Study on the reaction pathway in the vapor-phase hydrogenation of biomass-derived diethyl succinate over cuo/zno catalyst
文献类型：期刊论文
| 作者 | Ding, Guoqiang1,2; Zhu, Yulei1,3; Zheng, Hongyan3; Zhang, Wei1,2; Li, Yongwang1,3 |
| 刊名 | Catalysis communications
 |
| 出版日期 | 2010-08-25 |
| 卷号 | 11期号:14页码:1120-1124 |
| 关键词 | Diethyl succinate Hydrogenation Reaction pathway Ethyl 4-hydroxybutyl succinate |
| ISSN号 | 1566-7367 |
| DOI | 10.1016/j.catcom.2010.06.007 |
| 通讯作者 | Zhu, yulei(zhuyulei@sxicc.ac.cn) |
| 英文摘要 | The reactivity of biomass-derived diethyl succinate and its main reaction intermediates was separately investigated in a fixed-bed reactor over cuo/zno catalyst, and some interesting results were obtained. ethyl 4-hydroxybutyl succinate as an intermediate of diethyl succinate hydrogenation reaction was first detected, and it could be converted to 1,4-butanediol or polyesters. additionally, propanol and butanol are mainly derived from 1,4-butanediol rather than gamma-butyrolactone. a comprehensive reaction pathway for the hydrogenation of diethyl succinate is proposed, which is significant for the design of new catalytic formulations. a cuo/zno + hy admixed catalyst exhibiting excellent performance was prepared according to the proposed reaction pathway. (c) 2010 elsevier b.v. all rights reserved. |
| WOS关键词 | DIMETHYL MALEATE ; GAMMA-BUTYROLACTONE ; HYDROGENOLYSIS ; TETRAHYDROFURAN ; 1,4-BUTANEDIOL ; DEHYDROGENATION ; ANHYDRIDE ; ROUTE |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000281221500005 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2406592 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhu, Yulei |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China 3.Synfuels CHINA Co Ltd, Taiyuan 030032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ding, Guoqiang,Zhu, Yulei,Zheng, Hongyan,et al. Study on the reaction pathway in the vapor-phase hydrogenation of biomass-derived diethyl succinate over cuo/zno catalyst[J]. Catalysis communications,2010,11(14):1120-1124. |
| APA | Ding, Guoqiang,Zhu, Yulei,Zheng, Hongyan,Zhang, Wei,&Li, Yongwang.(2010).Study on the reaction pathway in the vapor-phase hydrogenation of biomass-derived diethyl succinate over cuo/zno catalyst.Catalysis communications,11(14),1120-1124. |
| MLA | Ding, Guoqiang,et al."Study on the reaction pathway in the vapor-phase hydrogenation of biomass-derived diethyl succinate over cuo/zno catalyst".Catalysis communications 11.14(2010):1120-1124. |
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来源：中国科学院大学
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