Hierarchical porous carbon obtained using the template of naoh-treated zeolite beta and its high performance as supercapacitor
文献类型:期刊论文
作者 | Xu, Huan; Gao, Qiuming; Guo, Hongliang; Wang, Huanlei |
刊名 | Microporous and mesoporous materials
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出版日期 | 2010-09-01 |
卷号 | 133期号:1-3页码:106-114 |
关键词 | Zeolite template Hierarchical porous carbon Supercapacitor |
ISSN号 | 1387-1811 |
DOI | 10.1016/j.micromeso.2010.04.021 |
通讯作者 | Gao, qiuming(qmgao@mail.sic.ac.cn) |
英文摘要 | Alkaline-treated zeolite beta (at-beta) has been taken as the template to prepare hierarchical porous carbons by a two-step casting process. the structures are characterized by x-ray diffraction, x-ray photoelectron spectroscopy, nitrogen sorption at 77 k and high-resolution transmission electron microcopy. the electrochemical performances of the supercapacitors tested by cyclic voltammetry and galvanostatic charge-discharge cycling are conducted in both aqueous and organic electrolytes. the carbon samples starting from at-beta (cn1 to cn3) exhibit higher capacitance retentions than the sample started from zeolite beta (cn) due to the different pore structures. in aqueous electrolyte, cn2 presents the best electrochemical performance which could be attributed to the highest accessible specific surface area. in organic electrolyte, cn shows the highest capacitance at low scan rate (or current load) consisting with the highest pseudocapacitance contribution of c-o quinone type groups (o-i), pyrrolic/pyridone (n-5) and pyridinic (n-6). (c) 2010 elsevier inc. all rights reserved. |
WOS关键词 | DOUBLE-LAYER CAPACITORS ; ORDERED MESOPOROUS CARBONS ; AREA MICROPOROUS CARBON ; ACTIVATED CARBON ; ELECTROCHEMICAL PERFORMANCE ; STRUCTURAL REGULARITY ; NANOPOROUS CARBON ; FUNCTIONAL-GROUPS ; NITROGEN ; ELECTRODE |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000279061000014 |
出版者 | ELSEVIER SCIENCE BV |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2407201 |
专题 | 中国科学院大学 |
通讯作者 | Gao, Qiuming |
作者单位 | Chinese Acad Sci, Shanghai Inst Ceram, Grad Sch, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Huan,Gao, Qiuming,Guo, Hongliang,et al. Hierarchical porous carbon obtained using the template of naoh-treated zeolite beta and its high performance as supercapacitor[J]. Microporous and mesoporous materials,2010,133(1-3):106-114. |
APA | Xu, Huan,Gao, Qiuming,Guo, Hongliang,&Wang, Huanlei.(2010).Hierarchical porous carbon obtained using the template of naoh-treated zeolite beta and its high performance as supercapacitor.Microporous and mesoporous materials,133(1-3),106-114. |
MLA | Xu, Huan,et al."Hierarchical porous carbon obtained using the template of naoh-treated zeolite beta and its high performance as supercapacitor".Microporous and mesoporous materials 133.1-3(2010):106-114. |
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来源:中国科学院大学
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