One-pot synthesis of propylene glycol and dipropylene glycol over strong basic catalyst
文献类型：期刊论文
| 作者 | Liu, Zhuo1,2; Zhao, Wenbo1; Xiao, Fukui1; Wei, Wei1; Sun, Yuhan1 |
| 刊名 | Catalysis communications
 |
| 出版日期 | 2010-03-31 |
| 卷号 | 11期号:8页码:675-678 |
| 关键词 | Propylene glycol Dipropylene glycol Strong basic catalyst na(2)o-zro(2) |
| ISSN号 | 1566-7367 |
| DOI | 10.1016/j.catcom.2010.01.004 |
| 通讯作者 | Wei, wei(weiwei@sxicc.ac.cn) |
| 英文摘要 | The synthesis of propylene glycol (pg) and dipropylene glycol (dpg) was carried out by the hydrolysis of propylene oxide over solid base catalysts. among them, sol-gel derived na(2)o-zro(2) showed the excellent performance. it was found that na(2)o-zro(2) had a mesoporous framework in which na(2)o nanoparticles were homogeneously dispersed. such a structure led to the strong basicity and then the excellent performance in the hydrolysis of propylene oxide. as a result, one-pot synthesis of propylene glycol (pg) and dipropylene glycol (dpg) could take place at a low h(2)o/po ratio of 3 without any condensation reactions. crown copyright (c) 2010 published by elsevier bm. all rights reserved. |
| WOS关键词 | SOLID BASE ; DIMETHYL CARBONATE ; ZIRCONIA ; METHANOL |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000276785000001 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2407574 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wei, Wei |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Zhuo,Zhao, Wenbo,Xiao, Fukui,et al. One-pot synthesis of propylene glycol and dipropylene glycol over strong basic catalyst[J]. Catalysis communications,2010,11(8):675-678. |
| APA | Liu, Zhuo,Zhao, Wenbo,Xiao, Fukui,Wei, Wei,&Sun, Yuhan.(2010).One-pot synthesis of propylene glycol and dipropylene glycol over strong basic catalyst.Catalysis communications,11(8),675-678. |
| MLA | Liu, Zhuo,et al."One-pot synthesis of propylene glycol and dipropylene glycol over strong basic catalyst".Catalysis communications 11.8(2010):675-678. |
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来源：中国科学院大学
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