Oxidative carbonylation of aniline with a mesoporous silica gel immobilised se-functionalised ionic liquid catalyst
文献类型：期刊论文
| 作者 | Ma, Yubo1,2; Shi, Feng1; Deng, Youquan1 |
| 刊名 | Journal of chemical research
 |
| 出版日期 | 2010-06-01 |
| 期号 | 6页码:344-347 |
| 关键词 | Silica gel Ionic liquids Selenium Non-phosgene Methyl phenyl carbamate |
| ISSN号 | 1747-5198 |
| DOI | 10.3184/030823410x12759267364502 |
| 通讯作者 | Deng, youquan(ydeng@licp.cas.cn) |
| 英文摘要 | A series of bmimbf(4)-templated mesoporous silica gel immobilised se-functionalised ionic liquids have been prepared. the catalysts were characterised by bet, ftir and icp-aes, and the results showed that the content of se increased from 2.7 to 4.76 wt% with pore volume increasing from 0.83 to 1.26 cm(3) g(-1). preliminary tests of this catalyst system on the carbonylation of aniline to afford methyl phenyl carbamate (mpc) indicated that good catalytic activity (higher than 74% aniline conversion with 99% mpc selectivity) could be achieved with higher than 150 mol h(-1) mol(-1) turnover frequency (tof). tof and aniline conversion slightly increased with increasing the content of se from 2.7 to 3.0 wt%, then decreased when the content of se increased to more than 3.0 wt%, this suggested that 2.7 to 3.0 wt% se content should be appropriate for mpc synthesis. the appropriate se content could be obtaineded by adjusting the range of pore volume of mesoporous silica gel from 0.83 to 0.85 cm(3) g(-1). in addition, the recycling test indicated that there was almost no deactivation of the catalyst when it was reused four times. |
| WOS关键词 | HIGHLY EFFICIENT PROMOTERS ; REDUCTIVE CARBONYLATION ; METHYL PHENYLCARBAMATE ; PHOSPHORUS-ACIDS ; CARBON-MONOXIDE ; PALLADIUM ; SELENIUM ; AMINES ; NITROBENZENE ; IMIDAZOLIUM |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000279865700013 |
| 出版者 | SCIENCE REVIEWS 2000 LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2407993 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Deng, Youquan |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Yubo,Shi, Feng,Deng, Youquan. Oxidative carbonylation of aniline with a mesoporous silica gel immobilised se-functionalised ionic liquid catalyst[J]. Journal of chemical research,2010(6):344-347. |
| APA | Ma, Yubo,Shi, Feng,&Deng, Youquan.(2010).Oxidative carbonylation of aniline with a mesoporous silica gel immobilised se-functionalised ionic liquid catalyst.Journal of chemical research(6),344-347. |
| MLA | Ma, Yubo,et al."Oxidative carbonylation of aniline with a mesoporous silica gel immobilised se-functionalised ionic liquid catalyst".Journal of chemical research .6(2010):344-347. |
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来源：中国科学院大学
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