Asymmetric transfer hydrogenation in water
文献类型：期刊论文
| 作者 | Tang Yuanfu1,2,3; Deng Jingen1,2 |
| 刊名 | Progress in chemistry
 |
| 出版日期 | 2010-07-01 |
| 卷号 | 22期号:7页码:1242-1253 |
| 关键词 | Chiral diamine Transition metal Aqueous media Asymmetric transfer hydrogenation |
| ISSN号 | 1005-281X |
| 通讯作者 | Deng jingen(jgdeng@cioc.ac.cn) |
| 英文摘要 | Asymmetric transfer hydrogenation (ath) has emerged as one of the most practical and powerful pathways to obtain chiral alcohols and amines, which are important fine chemicals. among the various catalysts for asymmetric transfer hydrogenation, the most efficient one is tsdpen-ru [tsdpen = n-(p-toluenesulfonyl)-1,2-diphenylethylenediamine] complex developed by noyori and coworkers. recently, with the increasing demanding for green chemistry, water was widely used as green solvent in asymmetric transfer hydrogenation, affording fast reaction rate, high enantioselectivity and good chemoselectivity. this review attempts to present an accounts of the progress made on asymmetric transfer hydrogenation of ketones, imines and activated olefins in water catalyzed by the complexes of unmodified and modified chiral diamines and transition metals, ruthenium [(cymene) rucl2](2), rhodium [(cp*)rhcl2](2) and iridium[(cp*)ircl2](2). |
| WOS关键词 | ENANTIOSELECTIVE TRANSFER HYDROGENATION ; SOLUBLE AMINOSULFONAMIDE LIGANDS ; AROMATIC KETONES ; RUTHENIUM COMPLEXES ; AQUEOUS-SOLUTION ; GREEN CHEMISTRY ; CARBONYL-COMPOUNDS ; TRANSFER REDUCTION ; BETA-CYCLODEXTRIN ; HIGHLY EFFICIENT |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000280274000002 |
| 出版者 | CHINESE ACAD SCIENCES |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2408030 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Deng Jingen |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Natl Engn Res Ctr Chiral Drugs, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang Yuanfu,Deng Jingen. Asymmetric transfer hydrogenation in water[J]. Progress in chemistry,2010,22(7):1242-1253. |
| APA | Tang Yuanfu,&Deng Jingen.(2010).Asymmetric transfer hydrogenation in water.Progress in chemistry,22(7),1242-1253. |
| MLA | Tang Yuanfu,et al."Asymmetric transfer hydrogenation in water".Progress in chemistry 22.7(2010):1242-1253. |
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来源：中国科学院大学
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