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Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and crystal structure of a new tetracopper complex [cu(h2o)(3)cu(hcdta)](2)(clo4)(2)center dot h2o

文献类型:期刊论文

作者Wang Mei-Xiang1,2; Dang Zhen-Hua1,2; Xu Li1
刊名Chinese journal of structural chemistry
出版日期2010
卷号29期号:4页码:551-554
关键词Copper Supramolecular Two-dimensional Weak interaction
ISSN号0254-5861
通讯作者Xu li(xli@ms.fjirsm.ac.cn)
英文摘要A new tetracopper complex [cu(h2o)(3)cu(hcdta)](2)(clo4)(2)center dot h2o (cdta = trans-cyclohexane-1,2-diamine-n,n,n',n'-tetraacetate) has been prepared and characterized by single-crystal x-ray diffraction analysis. the crystal adopts space group c2/c with a = 16.990(10), b = 9.150(5), c = 29.318(17) angstrom, beta = 104.289(9)degrees, v = 4417(4) angstrom(3), z = 4, c28h52cl2cu4n4o31, m-r = 1265.80, d-c = 1.904 g/cm(3), mu = 2.130 mm(-1), f(000) = 2584, t = 293(2) k, the final r = 0.0328 and wr = 0.0809 for 4938 observed reflections (i > 2 sigma(i)). the tetracopper units are interconnected by weak covalent bonds into a layered structure.
WOS关键词PERSPECTIVES ; MOLECULES
WOS研究方向Chemistry ; Crystallography
WOS类目Chemistry, Inorganic & Nuclear ; Crystallography
语种英语
WOS记录号WOS:000277342300009
出版者CHINESE JOURNAL STRUCTURAL CHEMISTRY
URI标识http://www.irgrid.ac.cn/handle/1471x/2408401
专题中国科学院大学
通讯作者Xu Li
作者单位1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Wang Mei-Xiang,Dang Zhen-Hua,Xu Li. Synthesis and crystal structure of a new tetracopper complex [cu(h2o)(3)cu(hcdta)](2)(clo4)(2)center dot h2o[J]. Chinese journal of structural chemistry,2010,29(4):551-554.
APA Wang Mei-Xiang,Dang Zhen-Hua,&Xu Li.(2010).Synthesis and crystal structure of a new tetracopper complex [cu(h2o)(3)cu(hcdta)](2)(clo4)(2)center dot h2o.Chinese journal of structural chemistry,29(4),551-554.
MLA Wang Mei-Xiang,et al."Synthesis and crystal structure of a new tetracopper complex [cu(h2o)(3)cu(hcdta)](2)(clo4)(2)center dot h2o".Chinese journal of structural chemistry 29.4(2010):551-554.

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来源:中国科学院大学

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