Synthesis of uv-curable polysiloxanes containing methacryloxy/fluorinated side groups and the performances of their cured composite coatings
文献类型：期刊论文
| 作者 | Tang, Chunyi1,2; Liu, Weiqu1; Ma, Songqi1,2; Wang, Zhengfang1,2; Hu, Chaohui1,2 |
| 刊名 | Progress in organic coatings
 |
| 出版日期 | 2010-12-01 |
| 卷号 | 69期号:4页码:359-365 |
| 关键词 | Polysiloxane Uv-curable Fluorinated group Composite coatings |
| ISSN号 | 0300-9440 |
| DOI | 10.1016/j.porgcoat.2010.07.009 |
| 通讯作者 | Liu, weiqu(liuwq@gic.ac.cn) |
| 英文摘要 | Three novel uv-curable polysiloxanes consisting of polysiloxane backbone with methacryloxy/fluorinated side groups were synthesized, and their structures were characterized by ft-ir, (1)h nmr and (13)c nmr. a series of uv-cured composite coatings based on the synthesized polysiloxanes and an epoxy methacrylate were obtained through photopolymerization. their gel content, flexibility, hardness, gloss, contact angle, thermal behavior as well as water absorption ratio were investigated. results found that the siloxane component could enhance the flexibility and gloss of coatings, while the presence of fluorinated groups could improve the hardness. the combination of silicon and fluorine in the same polymer could increase thermal stability and water resistance of the coatings and decrease their surface energy simultaneously. the observation of the fractured-surface morphology showed that the polysiloxanes could be well dispersed in the epoxy methacrylate to some extent. a suitable addition of such polysiloxane in photocurable coating matrixes may provide excellent properties for the cured coatings and widen their applications. crown copyright (c) 2010 published by elsevier b.v. all rights reserved. |
| WOS关键词 | EPOXY ; COPOLYMERS ; BEHAVIOR ; RESINS |
| WOS研究方向 | Chemistry ; Materials Science |
| WOS类目 | Chemistry, Applied ; Materials Science, Coatings & Films |
| 语种 | 英语 |
| WOS记录号 | WOS:000284814200009 |
| 出版者 | ELSEVIER SCIENCE SA |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2408710 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liu, Weiqu |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou 510650, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Chunyi,Liu, Weiqu,Ma, Songqi,et al. Synthesis of uv-curable polysiloxanes containing methacryloxy/fluorinated side groups and the performances of their cured composite coatings[J]. Progress in organic coatings,2010,69(4):359-365. |
| APA | Tang, Chunyi,Liu, Weiqu,Ma, Songqi,Wang, Zhengfang,&Hu, Chaohui.(2010).Synthesis of uv-curable polysiloxanes containing methacryloxy/fluorinated side groups and the performances of their cured composite coatings.Progress in organic coatings,69(4),359-365. |
| MLA | Tang, Chunyi,et al."Synthesis of uv-curable polysiloxanes containing methacryloxy/fluorinated side groups and the performances of their cured composite coatings".Progress in organic coatings 69.4(2010):359-365. |
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来源：中国科学院大学
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