A 2d layered thiostannate: synthesis and crystal structure of [tmdph(2)]sn3s7
文献类型：期刊论文
| 作者 | Wang Xin1,2; Sheng Tian-Lu1; Xiang Sheng-Chang1; Hu Sheng-Min1; Fu Rui-Biao1; Wu Xin-Tao1 |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2010 |
| 卷号 | 29期号:2页码:260-264 |
| 关键词 | Thiostannate Tmdp Crystal structure 2d layer (6,3) network |
| ISSN号 | 0254-5861 |
| 通讯作者 | Wu xin-tao(wxt@fjirsm.ac.cn) |
| 英文摘要 | A new thiostannate, [tmdph(2)]sn3s7 1 (tmdp = 4,4'-trimethylenedipiperidine), has been synthesized under solvothermal conditions and characterized by elemental analysis, ir spectroscopy, and single-crystal x-ray diffraction analysis. in 1, the sn3s4 secondary incomplete cubane-like building units are bridged by mu(2)-s atoms to form sn12s12 rings which are then joined parallelly to the [001] plane, giving the final 2d (sn3s72-)(n) layer of (6,3) network. the layers are stacked along the c axis so that 24-membered ring channels are generated, in which the organic cations are accommodated. the compound crystallizes in monoclinic, space group c2/c, with a = 23.052(3), b = 13.4039(12), c = 18.412(2) angstrom, beta = 120.112(4)degrees, v = 4921.3(9) angstrom(3), c13h28n2s7sn3, m-r = 792.86, z = 8, d-c = 2.140 g/cm(3), f(000) = 3056, mu = 3.619 mm(-1), the final r = 0.0488 and wr = 0.1125 for 4607 observed reflections with i > 2 sigma(i). |
| WOS关键词 | TIN(IV) SULFIDE ; COMPLEXES ; CHEMISTRY ; CLUSTERS ; SN |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000274809300016 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2408764 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu Xin-Tao |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Xin,Sheng Tian-Lu,Xiang Sheng-Chang,et al. A 2d layered thiostannate: synthesis and crystal structure of [tmdph(2)]sn3s7[J]. Chinese journal of structural chemistry,2010,29(2):260-264. |
| APA | Wang Xin,Sheng Tian-Lu,Xiang Sheng-Chang,Hu Sheng-Min,Fu Rui-Biao,&Wu Xin-Tao.(2010).A 2d layered thiostannate: synthesis and crystal structure of [tmdph(2)]sn3s7.Chinese journal of structural chemistry,29(2),260-264. |
| MLA | Wang Xin,et al."A 2d layered thiostannate: synthesis and crystal structure of [tmdph(2)]sn3s7".Chinese journal of structural chemistry 29.2(2010):260-264. |
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来源：中国科学院大学
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