Hydrophobically associating polyacrylamides prepared by inverse suspension polymerization: synthesis, characterization and aqueous solution properties
文献类型:期刊论文
作者 | Li, Xiaolan1,2; Liu, Xingli3; Chen, Quansheng1,2; Wang, Yu1,2; Feng, Yujun1 |
刊名 | Journal of macromolecular science part a-pure and applied chemistry
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出版日期 | 2010 |
卷号 | 47期号:4页码:358-367 |
关键词 | Inverse suspension polymerization Hydrophobically associating polyacrylamide Polymeric microspheres Hydrophobic interaction Solution properties |
ISSN号 | 1060-1325 |
DOI | 10.1080/10601320903539322 |
通讯作者 | Feng, yujun(yjfeng@cioc.ac.cn) |
英文摘要 | Hydrophobically associating polyacrylamides (hapams) were synthesized via inverse suspension polymerization using ammonium persulphate (aps)/tertramethylethylenediamine (temed) as the redox initiators, 2-methacryloyloxyethyl n-alkyl dimethyl ammonium bromide (dm-n, n = 8, 12, 16) as the hydrophobic comonomers. the structures of the copolymers were elucidated by ft-ir and ionic chromatographic analysis, respectively. the morphology and particle size of the resultant hapams were characterized by scanning electronic microscope (sem) and laser particle size analyzer, which revealed that spherical particles were formed and the particle size exhibited gaussian distribution centered from 25 m to 162 m. furthermore, the solution properties of the copolymers were studied with viscometry and the results showed that hapams synthesized under optimal conditions exhibited an obvious viscosity enhancement in aqueous solution and excellent salt-tolerant capability in brine. |
WOS关键词 | SURFACE-ACTIVE MONOMERS ; POST-MODIFICATION ; DIMETHYLAMINOETHYL METHACRYLATE ; MICELLAR COPOLYMERIZATION ; FLOCCULATION PROPERTIES ; RHEOLOGICAL BEHAVIOR ; OIL-RECOVERY ; ALKYL SALTS ; WATER ; ACRYLAMIDE |
WOS研究方向 | Polymer Science |
WOS类目 | Polymer Science |
语种 | 英语 |
WOS记录号 | WOS:000274554000009 |
出版者 | TAYLOR & FRANCIS INC |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2409180 |
专题 | 中国科学院大学 |
通讯作者 | Feng, Yujun |
作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.SW Univ Nationalities, Coll Chem & Environm Protect Engn, Chengdu 610041, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Xiaolan,Liu, Xingli,Chen, Quansheng,et al. Hydrophobically associating polyacrylamides prepared by inverse suspension polymerization: synthesis, characterization and aqueous solution properties[J]. Journal of macromolecular science part a-pure and applied chemistry,2010,47(4):358-367. |
APA | Li, Xiaolan,Liu, Xingli,Chen, Quansheng,Wang, Yu,&Feng, Yujun.(2010).Hydrophobically associating polyacrylamides prepared by inverse suspension polymerization: synthesis, characterization and aqueous solution properties.Journal of macromolecular science part a-pure and applied chemistry,47(4),358-367. |
MLA | Li, Xiaolan,et al."Hydrophobically associating polyacrylamides prepared by inverse suspension polymerization: synthesis, characterization and aqueous solution properties".Journal of macromolecular science part a-pure and applied chemistry 47.4(2010):358-367. |
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来源:中国科学院大学
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