中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Catalytic dehydrogenation of isobutane in the presence of carbon dioxide over nickel supported on active carbon

文献类型:期刊论文

作者Ding, Jianfei1,2; Qin, Zhangfeng1; Li, Xuekuan1; Wang, Guofu1; Wang, Jianguo1
刊名Journal of molecular catalysis a-chemical
出版日期2010-01-15
卷号315期号:2页码:221-225
关键词Dehydrogenation Isobutane Carbon dioxide Nio/ac Isobutene Nickel species
ISSN号1381-1169
DOI10.1016/j.molcata.2009.09.015
通讯作者Wang, jianguo()
英文摘要The dehydrogenation of isobutane to isobutene was carried out in the presence of carbon dioxide over the catalyst nickel supported oil active carbon (ac) the state and property of nickel species (niox) in the catalyst are relevant to its calcination temperature, because no may be partially reduced to ni by ac at high temperature no and ni species are different in the catalytic behaviors: ni is only effective for direct dehydrogenation of isobutane. while no is also highly active for the coupled dehydrogenation with carbon dioxide carbon dioxide can significantly enhance the dehydrogenation of isobutane over nio/ac through keeping nio species, in situ eliminating hydrogen produced and suppressing coke formation. (c) 2009 elsevier b.v. all rights reserved.
WOS关键词OXIDATIVE DEHYDROGENATION ; OXIDE CATALYSTS ; OXYDEHYDROGENATION ; PERFORMANCE ; CONVERSION ; ETHANE
WOS研究方向Chemistry
WOS类目Chemistry, Physical
语种英语
WOS记录号WOS:000272561300013
出版者ELSEVIER SCIENCE BV
URI标识http://www.irgrid.ac.cn/handle/1471x/2409286
专题中国科学院大学
通讯作者Wang, Jianguo
作者单位1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Ding, Jianfei,Qin, Zhangfeng,Li, Xuekuan,et al. Catalytic dehydrogenation of isobutane in the presence of carbon dioxide over nickel supported on active carbon[J]. Journal of molecular catalysis a-chemical,2010,315(2):221-225.
APA Ding, Jianfei,Qin, Zhangfeng,Li, Xuekuan,Wang, Guofu,&Wang, Jianguo.(2010).Catalytic dehydrogenation of isobutane in the presence of carbon dioxide over nickel supported on active carbon.Journal of molecular catalysis a-chemical,315(2),221-225.
MLA Ding, Jianfei,et al."Catalytic dehydrogenation of isobutane in the presence of carbon dioxide over nickel supported on active carbon".Journal of molecular catalysis a-chemical 315.2(2010):221-225.

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