Catalytic dehydrogenation of isobutane in the presence of carbon dioxide over nickel supported on active carbon
文献类型:期刊论文
作者 | Ding, Jianfei1,2; Qin, Zhangfeng1; Li, Xuekuan1; Wang, Guofu1; Wang, Jianguo1 |
刊名 | Journal of molecular catalysis a-chemical
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出版日期 | 2010-01-15 |
卷号 | 315期号:2页码:221-225 |
关键词 | Dehydrogenation Isobutane Carbon dioxide Nio/ac Isobutene Nickel species |
ISSN号 | 1381-1169 |
DOI | 10.1016/j.molcata.2009.09.015 |
通讯作者 | Wang, jianguo() |
英文摘要 | The dehydrogenation of isobutane to isobutene was carried out in the presence of carbon dioxide over the catalyst nickel supported oil active carbon (ac) the state and property of nickel species (niox) in the catalyst are relevant to its calcination temperature, because no may be partially reduced to ni by ac at high temperature no and ni species are different in the catalytic behaviors: ni is only effective for direct dehydrogenation of isobutane. while no is also highly active for the coupled dehydrogenation with carbon dioxide carbon dioxide can significantly enhance the dehydrogenation of isobutane over nio/ac through keeping nio species, in situ eliminating hydrogen produced and suppressing coke formation. (c) 2009 elsevier b.v. all rights reserved. |
WOS关键词 | OXIDATIVE DEHYDROGENATION ; OXIDE CATALYSTS ; OXYDEHYDROGENATION ; PERFORMANCE ; CONVERSION ; ETHANE |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
语种 | 英语 |
WOS记录号 | WOS:000272561300013 |
出版者 | ELSEVIER SCIENCE BV |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2409286 |
专题 | 中国科学院大学 |
通讯作者 | Wang, Jianguo |
作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Ding, Jianfei,Qin, Zhangfeng,Li, Xuekuan,et al. Catalytic dehydrogenation of isobutane in the presence of carbon dioxide over nickel supported on active carbon[J]. Journal of molecular catalysis a-chemical,2010,315(2):221-225. |
APA | Ding, Jianfei,Qin, Zhangfeng,Li, Xuekuan,Wang, Guofu,&Wang, Jianguo.(2010).Catalytic dehydrogenation of isobutane in the presence of carbon dioxide over nickel supported on active carbon.Journal of molecular catalysis a-chemical,315(2),221-225. |
MLA | Ding, Jianfei,et al."Catalytic dehydrogenation of isobutane in the presence of carbon dioxide over nickel supported on active carbon".Journal of molecular catalysis a-chemical 315.2(2010):221-225. |
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来源:中国科学院大学
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