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Estimation of ultra-stability of methane hydrate at 1 atm by thermal conductivity measurement

文献类型:期刊论文

作者Li, Dongliang1,2,3,4; Liang, Deqing1,2,3; Fan, Shuanshi3; Peng, Hao1,2
刊名Journal of natural gas chemistry
出版日期2010-05-01
卷号19期号:3页码:229-233
关键词Methane hydrate Self-preservation Dissociation velocity Thermal conductivity
ISSN号1003-9953
DOI10.1016/s1003-9953(09)60070-0
通讯作者Liang, deqing(liangdq@ms.giec.ac.cn)
英文摘要Thermal conductivity of methane hydrate was measured in hydrate dissociation self-preservation zone by means of the transient plane source (tps) technique developed by gustafsson. the sample was formed from 99.9% (volume ratio) methane gas with 280 ppm sodium dodecyl sulfate (sds) solution under 6.6 mpa and 273.15 k. the methane hydrate sample was taken out of the cell and moved into a low temperature chamber when the conversion ratio of water was more than 90%. in order to measure the thermal conductivity, the sample was compacted into two columnar parts by compact tool at 268.15 k. the measurements are carried out in the temperature ranging from 263.15 k to 271.15 k at atmospheric pressure. additionally, the relationship between thermal conductivity and time is also investigated at 263.15 k and 268.15 k, respectively. in 24 h, thermal conductivity increases only 5.45% at 268.15 k, but thermal conductivity increases 196.29% at 263.15 k. methane hydrates exhibit only minimal decomposition at 1 atm and the temperature ranging from 263.15 k to 271.15k. at 1 atm and 268.15 k, the total gas that evolved after 24 h was amounted to less than 0.71% of the originally stored gas, and this ultra-stability was maintained if the test was lasted for more than two hundreds hours before terminating.
WOS关键词GAS ; PRESERVATION ; DISSOCIATION ; ICE
WOS研究方向Chemistry ; Energy & Fuels ; Engineering
WOS类目Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
语种英语
WOS记录号WOS:000278975700005
出版者ELSEVIER SCIENCE BV
URI标识http://www.irgrid.ac.cn/handle/1471x/2409308
专题中国科学院大学
通讯作者Liang, Deqing
作者单位1.CAS, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.CAS, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
3.MOE, Key Lab Enhanced Heat Transfer & Energy Conservat, Guangzhou 510640, Guangdong, Peoples R China
4.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Li, Dongliang,Liang, Deqing,Fan, Shuanshi,et al. Estimation of ultra-stability of methane hydrate at 1 atm by thermal conductivity measurement[J]. Journal of natural gas chemistry,2010,19(3):229-233.
APA Li, Dongliang,Liang, Deqing,Fan, Shuanshi,&Peng, Hao.(2010).Estimation of ultra-stability of methane hydrate at 1 atm by thermal conductivity measurement.Journal of natural gas chemistry,19(3),229-233.
MLA Li, Dongliang,et al."Estimation of ultra-stability of methane hydrate at 1 atm by thermal conductivity measurement".Journal of natural gas chemistry 19.3(2010):229-233.

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来源:中国科学院大学

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