Bi3in4s10 and bi14.7in11.3s38: two new bismuth sulfides with interesting bi-bi bonding
文献类型：期刊论文
| 作者 | Yin, Wenlong1,2,3; Mei, Dajiang1,2,3; Yao, Jiyong1,2; Fu, Peizhen1,2; Wu, Yicheng1,2 |
| 刊名 | Journal of solid state chemistry
 |
| 出版日期 | 2010-11-01 |
| 卷号 | 183期号:11页码:2544-2551 |
| 关键词 | Bismuth Indium Sulfide Crystal structure Optical |
| ISSN号 | 0022-4596 |
| DOI | 10.1016/j.jssc.2010.08.028 |
| 通讯作者 | Yao, jiyong(jyao@mail.ipc.ac.cn) |
| 英文摘要 | Two new ternary bismuth chalcogenides, bi3in4s10 and bi14.7in11.3s38, were synthesized from the reactions of binary sulfides via a two-step flux technique. single-crystal x-ray diffraction analyses indicate that bi3in4s10 crystallizes in the non-centrosymmetric space group pm and bi14.7in11.3s38 crystallizes in the centrosymmetric space group p2(1)/m. both compounds adopt three-dimensional frameworks. a distinct structural feature in the two structures is the presence of chains of bi atoms with alternating short bi-bi bonds of around 3.1 angstrom and longer distances of around 4.6 angstrom. the optical band gaps of 1.42(2) ev for bi3in4s10 and 1.45(2) ev for bi14.7in11.3s38 were deduced from the diffuse reflectance spectra. (c) 2010 elsevier inc. all rights reserved. |
| WOS关键词 | COMPOSITE CRYSTAL-STRUCTURE ; 2ND-HARMONIC GENERATION ; THERMOELECTRIC-MATERIAL ; OPTICAL-PROPERTIES ; TERNARY SULFIDE ; INDIUM SULFIDE ; SYSTEM ; SE ; CHALCOGENIDES ; CHEMISTRY |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000284179800006 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2409875 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yao, Jiyong |
| 作者单位 | 1.Chinese Acad Sci, Ctr Crystal Res & Dev, Tech Inst Phys & Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Key Lab Funct Crystals & Laser Technol, Beijing 100190, Peoples R China 3.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yin, Wenlong,Mei, Dajiang,Yao, Jiyong,et al. Bi3in4s10 and bi14.7in11.3s38: two new bismuth sulfides with interesting bi-bi bonding[J]. Journal of solid state chemistry,2010,183(11):2544-2551. |
| APA | Yin, Wenlong,Mei, Dajiang,Yao, Jiyong,Fu, Peizhen,&Wu, Yicheng.(2010).Bi3in4s10 and bi14.7in11.3s38: two new bismuth sulfides with interesting bi-bi bonding.Journal of solid state chemistry,183(11),2544-2551. |
| MLA | Yin, Wenlong,et al."Bi3in4s10 and bi14.7in11.3s38: two new bismuth sulfides with interesting bi-bi bonding".Journal of solid state chemistry 183.11(2010):2544-2551. |
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来源：中国科学院大学
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