Zintl phase yb1-xcaxcd2sb2 with tunable thermoelectric properties induced by cation substitution
文献类型：期刊论文
| 作者 | Cao, Qi-Gao2,3; Zhang, Hui2; Tang, Mei-Bo2; Chen, Hao-Hong2; Yang, Xin-Xin2; Grin, Yuri1; Zhao, Jing-Tai2 |
| 刊名 | Journal of applied physics
 |
| 出版日期 | 2010-03-01 |
| 卷号 | 107期号:5页码:5 |
| ISSN号 | 0021-8979 |
| DOI | 10.1063/1.3327443 |
| 通讯作者 | Grin, yuri(grin@cpfs.mpg.de) |
| 英文摘要 | It has been shown previously that the thermoelectric properties of the zintl phase compound ybcd2sb2 can be finely tuned via zn substitution at the cd-site in the anionic (cd2sb2)(2-) framework. here we report the results of the investigation of isoelectronic substitution of yb by ca. the p-type yb1-xcaxcd2sb2 (0.2 <= x <= 0.8) samples have been synthesized via a solid-state reaction followed by suitable cooling, annealing, grinding, and spark plasma sintering densification processes. in samples with x=0.2, 0.4, 0.5, 0.6, 0.8, the electrical conductivity, seebeck coefficient, and thermal conductivity measurements have been carried out in the temperature range from 300 to 650 k. it is found that the ca substitution effectively lowers the thermal conductivity for all samples at high temperature, while it significantly increases the seebeck coefficient. as a result, the dimensionless figure of merit zt of 0.96 has been attained at 650 k for samples with x=0.4, while the value is 0.78 for the unsubstituted ybcd2sb2 (c) 2010 american institute of physics. [doi:10.1063/1.3327443] |
| WOS关键词 | CACD2SB2 |
| WOS研究方向 | Physics |
| WOS类目 | Physics, Applied |
| 语种 | 英语 |
| 出版者 | AMER INST PHYSICS |
| WOS记录号 | WOS:000275657500066 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2410438 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Grin, Yuri |
| 作者单位 | 1.Max Planck Inst Chem Phys Fester Stoffe, D-01187 Dresden, Germany 2.Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Transparent Optofunct Inorgan Mat, Shanghai 200050, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao, Qi-Gao,Zhang, Hui,Tang, Mei-Bo,et al. Zintl phase yb1-xcaxcd2sb2 with tunable thermoelectric properties induced by cation substitution[J]. Journal of applied physics,2010,107(5):5. |
| APA | Cao, Qi-Gao.,Zhang, Hui.,Tang, Mei-Bo.,Chen, Hao-Hong.,Yang, Xin-Xin.,...&Zhao, Jing-Tai.(2010).Zintl phase yb1-xcaxcd2sb2 with tunable thermoelectric properties induced by cation substitution.Journal of applied physics,107(5),5. |
| MLA | Cao, Qi-Gao,et al."Zintl phase yb1-xcaxcd2sb2 with tunable thermoelectric properties induced by cation substitution".Journal of applied physics 107.5(2010):5. |
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来源：中国科学院大学
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