Chiral phosphoric acid catalyzed diastereo- and enantioselective 1,4-conjugate addition of beta-ketoesters to nitroolefins
文献类型：期刊论文
| 作者 | Zhang, Hui1,2; Cun, Lin-Feng1; Zhang, Xiao-Mei1; Yuan, Wei-Cheng1 |
| 刊名 | Letters in organic chemistry
 |
| 出版日期 | 2010-04-01 |
| 卷号 | 7期号:3页码:219-225 |
| 关键词 | Chiral phosphoric acid Organocatalysis Asymmetric catalysis 1,4-conjugate addition Beta-ketoesters Nitroolefins |
| ISSN号 | 1570-1786 |
| 通讯作者 | Yuan, wei-cheng(yuanwc@cioc.ac.cn) |
| 英文摘要 | Chiral phosphoric acid as organocatalyst for the diastereo- and enantioselectivity 1,4-conjugate addition of a variety of beta-ketoesters to nitroolefins was firstly developed, providing the corresponding adducts in high yield (up to 97%) with moderate diastereoselectivities (up to 2.6:1 dr) and enantioselectivities (up to 58% ee). |
| WOS关键词 | MANNICH-TYPE REACTION ; ASYMMETRIC CONJUGATE ADDITION ; FRIEDEL-CRAFTS ALKYLATION ; DIELS-ALDER REACTION ; BRONSTED ACID ; MICHAEL ADDITIONS ; 1,3-DICARBONYL COMPOUNDS ; ACYCLIC NITROALKENES ; ORGANOBORONIC ACIDS ; KETONES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000277156400008 |
| 出版者 | BENTHAM SCIENCE PUBL LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2410664 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yuan, Wei-Cheng |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Sichuan Prov, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Hui,Cun, Lin-Feng,Zhang, Xiao-Mei,et al. Chiral phosphoric acid catalyzed diastereo- and enantioselective 1,4-conjugate addition of beta-ketoesters to nitroolefins[J]. Letters in organic chemistry,2010,7(3):219-225. |
| APA | Zhang, Hui,Cun, Lin-Feng,Zhang, Xiao-Mei,&Yuan, Wei-Cheng.(2010).Chiral phosphoric acid catalyzed diastereo- and enantioselective 1,4-conjugate addition of beta-ketoesters to nitroolefins.Letters in organic chemistry,7(3),219-225. |
| MLA | Zhang, Hui,et al."Chiral phosphoric acid catalyzed diastereo- and enantioselective 1,4-conjugate addition of beta-ketoesters to nitroolefins".Letters in organic chemistry 7.3(2010):219-225. |
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来源：中国科学院大学
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