"green" electrochemical synthesis of pt/graphene sheet nanocomposite film and its electrocatalytic property
文献类型:期刊论文
作者 | Liu, Sheng1,2; Wang, Jinqing1; Zeng, Jing3; Ou, Junfei1,2; Li, Zhangpeng1,2; Liu, Xiaohong1; Yang, Shengrong1 |
刊名 | Journal of power sources
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出版日期 | 2010-08-01 |
卷号 | 195期号:15页码:4628-4633 |
关键词 | Pt/graphene nanocomposite film Electrophoretic deposition Electrochemical synthesis Methanol oxidation Fuel cell |
ISSN号 | 0378-7753 |
DOI | 10.1016/j.jpowsour.2010.02.024 |
通讯作者 | Wang, jinqing(jqwang@licp.cas.cn) |
英文摘要 | Nanocomposite films of platinum nanoparticle-deposited expandable graphene sheet (pt/egs) are fabricated on conductive indium tin oxide glass electrodes via a "green" electrochemical synthetic route involving a series of electrochemical processes. the microstructure and morphology of the prepared film samples are characterized by fourier transform infrared spectroscopy. raman spectroscopy, x-ray photoelectron spectroscopy, x-ray diffraction, three-dimensional non-contact surface mapping, and field emission scanning electron microscopy. at the same time, the catalytic activity and stability of the pt/egs film for the oxidation of methanol are evaluated through cyclic voltammetry and chronoamperometry tests. the pt nanoparticles in the pt/egs nanocomposite film are found to be uniformly distributed on the egs. the as-synthesized pt/egs nanocomposite exhibits high catalytic activity and good stability for the oxidation of methanol, which may be attributed to its excellent electrical conductivity and the high specific surface area of the graphene sheet catalyst support. (c) 2010 elsevier b.v. all rights reserved. |
WOS关键词 | GRAPHITE-OXIDE ; ELECTROPHORETIC DEPOSITION ; METHANOL OXIDATION ; GRAPHENE ; REDUCTION ; SUPERCAPACITORS ; SPECTROSCOPY ; ELECTRODES |
WOS研究方向 | Electrochemistry ; Energy & Fuels |
WOS类目 | Electrochemistry ; Energy & Fuels |
语种 | 英语 |
WOS记录号 | WOS:000277820500010 |
出版者 | ELSEVIER SCIENCE BV |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2410679 |
专题 | 中国科学院大学 |
通讯作者 | Wang, Jinqing |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Sheng,Wang, Jinqing,Zeng, Jing,et al. "green" electrochemical synthesis of pt/graphene sheet nanocomposite film and its electrocatalytic property[J]. Journal of power sources,2010,195(15):4628-4633. |
APA | Liu, Sheng.,Wang, Jinqing.,Zeng, Jing.,Ou, Junfei.,Li, Zhangpeng.,...&Yang, Shengrong.(2010)."green" electrochemical synthesis of pt/graphene sheet nanocomposite film and its electrocatalytic property.Journal of power sources,195(15),4628-4633. |
MLA | Liu, Sheng,et al.""green" electrochemical synthesis of pt/graphene sheet nanocomposite film and its electrocatalytic property".Journal of power sources 195.15(2010):4628-4633. |
入库方式: iSwitch采集
来源:中国科学院大学
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