Synthesis and catalytic properties of meapo-5 molecular sieves for selective oxidation of cinnamyl alcohol
文献类型：期刊论文
| 作者 | He Yue1,2; Dong Mei1; Li Jun-Fen1; Wang Jian-Guo1; Fan Wei-Bin1 |
| 刊名 | Acta physico-chimica sinica
 |
| 出版日期 | 2010-05-01 |
| 卷号 | 26期号:5页码:1305-1310 |
| 关键词 | Selective oxidation Aluminphosphate molecular sieves Hydrothermal synthesis Meapo-5 Cinnamyl alcohol |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/pku.whxb20100517 |
| 通讯作者 | Dong mei(mdong@sxicc.ac.cn) |
| 英文摘要 | A series of metal ion. substituted aluminophosphate molecular sieves of meapo-5 (me = co, fe, cu, zn, mn) were hydrothermally synthesized. the as. synthesized and calcined samples were characterized by x. ray diffraction (xrd), diffuse reflectance (dr) uv-vis spectroscopy, thermogravimetric. differential thermal analysis (tg-dta), and inductively coupled plasma. atomic emission spectroscopy (icp-aes) techniques. the as. synthesized single. phase meapo-5 molecular sieves all had high crystallinities. the type of metal significantly influences the states and amounts of the incorporated metal species, as indicated by dr uv-vis and icp analysis results. co2+, zn2+, fe3+, and mn2+ can be incorporated into the framework through the substitution of al3+, while cu2+ substitution is difficult. selective oxidation of cinnamyl alcohol with molecular oxygen over various meapo-5 molecular sieves was conducted to probe the effects of the nature and states of metal species on their catalytic performances. coapo-5 showed higher catalytic activity and selectivity than the other meapo-5 molecular sieves. 1,4-dioxane should be of the choice of solvent. a decrease in the reaction temperature favors the formation of cinnamaldehyde whereas an increase in the reaction temperature remarkably promotes the epoxidation of cinnamyl alcohol regardless of the occurrence of deep oxidation processes. |
| WOS关键词 | PHENOL HYDROXYLATION ; COAPO-5 ; PERFORMANCE ; EPOXIDATION ; VAPO |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000277881600019 |
| 出版者 | PEKING UNIV PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2410683 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Dong Mei |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | He Yue,Dong Mei,Li Jun-Fen,et al. Synthesis and catalytic properties of meapo-5 molecular sieves for selective oxidation of cinnamyl alcohol[J]. Acta physico-chimica sinica,2010,26(5):1305-1310. |
| APA | He Yue,Dong Mei,Li Jun-Fen,Wang Jian-Guo,&Fan Wei-Bin.(2010).Synthesis and catalytic properties of meapo-5 molecular sieves for selective oxidation of cinnamyl alcohol.Acta physico-chimica sinica,26(5),1305-1310. |
| MLA | He Yue,et al."Synthesis and catalytic properties of meapo-5 molecular sieves for selective oxidation of cinnamyl alcohol".Acta physico-chimica sinica 26.5(2010):1305-1310. |
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来源：中国科学院大学
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