Investigation on properties of new fluorine- and silicon-modified uv-cured epoxy methacrylate resin
文献类型：期刊论文
| 作者 | Tang, Chunyi1,2; Liu, Weiqu1 |
| 刊名 | Journal of applied polymer science
 |
| 出版日期 | 2010-08-05 |
| 卷号 | 117期号:3页码:1859-1866 |
| 关键词 | Side methacryloxy group polysiloxane 2,2,3,4,4,4-hexafluorobutyl methacrylate Bisphenol-a epoxy methacrylate Uv-cure Composite film |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.32164 |
| 通讯作者 | Liu, weiqu(liuwq@gic.ac.cn) |
| 英文摘要 | Photosensitive organofluorine and organosilicon play a key role in improving the properties of uv-curing coating materials. in this study, by using 2,2,3,4,4,4-hexafluorobutyl methacrylate (hfma) and a synthesized side methacryloxy group polysiloxane (maps) as modifying materials and bisphenol-a epoxy methacrylate (bema) as matrix, respectively, a innovative uv-curing system, bema/hfma/maps composite system was developed. through uv-cure process, a series of bema/hfma, bema/maps, and bema/hfma/maps cured composite films with different proportions were successfully obtained. it was found that hfma monomer was helpful for the reduction of the surface energy of the uv-cured composite films and the enhancement of their water resistance property. without hfma in bema matrix, maps could facilitate the improvement of the properties of bema/maps cured films, and the presence of maps in bema/hfma/maps system could significantly decrease the surface energy of the cured films to 22.1 mj/m(2) and improve their thermal stabilities and water resistance properties by measurements, contact angle, tga, dsc, and water resistance. to the sem observation, hfma and maps were well distributed in the cured films in favor of their excellent performances. (c) 2010 wiley periodicals, inc. j appl polym sci 117: 1859-1866, 2010 |
| WOS关键词 | NANOCOMPOSITES ; POLYSILOXANE ; COPOLYMERS ; POLYESTER ; COATINGS ; BEHAVIOR ; CLAY |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000278571200074 |
| 出版者 | JOHN WILEY & SONS INC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2410894 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liu, Weiqu |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou 510650, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Chunyi,Liu, Weiqu. Investigation on properties of new fluorine- and silicon-modified uv-cured epoxy methacrylate resin[J]. Journal of applied polymer science,2010,117(3):1859-1866. |
| APA | Tang, Chunyi,&Liu, Weiqu.(2010).Investigation on properties of new fluorine- and silicon-modified uv-cured epoxy methacrylate resin.Journal of applied polymer science,117(3),1859-1866. |
| MLA | Tang, Chunyi,et al."Investigation on properties of new fluorine- and silicon-modified uv-cured epoxy methacrylate resin".Journal of applied polymer science 117.3(2010):1859-1866. |
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来源：中国科学院大学
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