Synthesis of oxyresveratrol
文献类型：期刊论文
| 作者 | Sun Hongyi1,2,3; Xiao Chunfen1,2,3; Wei Wen1; Chen Yu1,2,3; Lue Zeliang1,2,3; Zou Yong1 |
| 刊名 | Chinese journal of organic chemistry
 |
| 出版日期 | 2010-10-01 |
| 卷号 | 30期号:10页码:1574-1579 |
| 关键词 | Oxyresveratrol Phenylacetic acid Willgerodt-kindler rearrangement Methylation Perkin reaction Decarboxylation Demethylation |
| ISSN号 | 0253-2786 |
| 通讯作者 | Sun hongyi() |
| 英文摘要 | A convenient method for the practical synthesis of oxyresveratrol is described. starting from the readily available 3,5-dihydroxyacetophenone (1), 3,5-dimethoxyphenylacetic acid (3) can be achieved through methylation and willgerodt-kindler rearrangement. perkin condensation between 3 and 2,4-dimethoxybenzaldehyde (4) formed the stilbene skeleton, and by subsequent decarboxylation and demethylation/isomerization process, oxyresveratrol (7) was obtained in an overall yield of 30%. the synthetic method has several advantages such as mild reaction conditions, high yield of product and simple operations. the structures of the target compound and key intermediates were verified by ms, ir, (1)h nmr and (13)c nmr techniques. |
| WOS关键词 | RESVERATROL ; CELLS ; CIS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000283962200023 |
| 出版者 | SCIENCE CHINA PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2411168 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Sun Hongyi |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou 510650, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Qujing Normal Univ, Dept Chem & Chem Engn, Qujing 655011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun Hongyi,Xiao Chunfen,Wei Wen,et al. Synthesis of oxyresveratrol[J]. Chinese journal of organic chemistry,2010,30(10):1574-1579. |
| APA | Sun Hongyi,Xiao Chunfen,Wei Wen,Chen Yu,Lue Zeliang,&Zou Yong.(2010).Synthesis of oxyresveratrol.Chinese journal of organic chemistry,30(10),1574-1579. |
| MLA | Sun Hongyi,et al."Synthesis of oxyresveratrol".Chinese journal of organic chemistry 30.10(2010):1574-1579. |
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来源：中国科学院大学
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