Fischer-tropsch synthesis in polyethylene glycol with amorphous iron nanocatalysts prepared by chemical reduction in various solvents
文献类型：期刊论文
| 作者 | Cheng, Xiaofan1,2,3; Wu, Baoshan1,2; Yang, Yong1,2; Xiang, Hongwei1,2; Li, Yongwang1,2 |
| 刊名 | Journal of molecular catalysis a-chemical
 |
| 出版日期 | 2010-08-17 |
| 卷号 | 329期号:1-2页码:103-109 |
| 关键词 | Amorphous fe-b nanoalloys Ethylene glycol Water Polyethylene glycol Fischer-tropsch synthesis |
| ISSN号 | 1381-1169 |
| DOI | 10.1016/j.molcata.2010.06.024 |
| 通讯作者 | Wu, baoshan(wbs@sxicc.ac.cn) |
| 英文摘要 | Amorphous iron nanocatalysts were prepared by chemical reduction using various solvents and dispersed in polyethylene glycol (peg) for fischer-tropsch synthesis (h's). the results indicated that the as-prepared catalysts were mainly amorphous fe-b or fe-b/alpha-fe nanoalloys with a surface layer of oxides of iron and boron. the preparation solvents had a significant influence on the morphology, phase composition and surface property of these catalysts. under reaction conditions of 3.0 mpa syngas (h(2)/co = 2) and 200 degrees c, the catalyst prepared in water exhibited the highest fts activity (0.83 molco mol(fe)(-1) h(-1)). this high activity is attributed to its high iron content and extent of reduction on the surface as well as high iron carbides formed during reaction. the products or catalysts can be easily separated after reaction. (c) 2010 elsevier b.v. all rights reserved. |
| WOS关键词 | IONIC LIQUIDS ; CATALYSTS ; HYDROGENATION ; WATER ; FE ; PHASE ; NANOCLUSTERS ; SELECTIVITY ; ETHANOL ; CARBON |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000281321000015 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2411621 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Baoshan |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China 2.Chinese Acad Sci, Inst Coal Chem, Natl Engn Lab Indirect Coal Liquefact, Taiyuan 030001, Shanxi, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, Xiaofan,Wu, Baoshan,Yang, Yong,et al. Fischer-tropsch synthesis in polyethylene glycol with amorphous iron nanocatalysts prepared by chemical reduction in various solvents[J]. Journal of molecular catalysis a-chemical,2010,329(1-2):103-109. |
| APA | Cheng, Xiaofan,Wu, Baoshan,Yang, Yong,Xiang, Hongwei,&Li, Yongwang.(2010).Fischer-tropsch synthesis in polyethylene glycol with amorphous iron nanocatalysts prepared by chemical reduction in various solvents.Journal of molecular catalysis a-chemical,329(1-2),103-109. |
| MLA | Cheng, Xiaofan,et al."Fischer-tropsch synthesis in polyethylene glycol with amorphous iron nanocatalysts prepared by chemical reduction in various solvents".Journal of molecular catalysis a-chemical 329.1-2(2010):103-109. |
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来源：中国科学院大学
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