Synthesis of propylene carbonate from co2 and propylene oxide with ki and inorganic ammonium salts as catalyst
文献类型：期刊论文
| 作者 | Zhou Xi1,2; Yang Xiangui1; Yao Jie1; Wang Gongying1 |
| 刊名 | Acta chimica sinica
 |
| 出版日期 | 2010-05-14 |
| 卷号 | 68期号:9页码:870-874 |
| 关键词 | Carbon dioxide Propylene oxide Propylene carbonate Potassium iodide Inorganic ammonium salt |
| ISSN号 | 0567-7351 |
| 通讯作者 | Zhou xi() |
| 英文摘要 | Synthesis of propylene carbonate (pc) from co2 and propylene oxide catalyzed by potassium halide (kcl, kbr, ki) in the presence of inorganic ammonium salt (ammonium carbamate, ammonium bicarbonate, ammonium carbonate) was studied. it was discovered that potassium halide and inorganic ammonium salt showed excellent synergetic catalytic effect, and ammonium carbamate showed the best co-catalytic effect among of them when ki was used as main catalyst for pc synthesis. effects of amount of catalyst, reaction temperature, co2 initial pressure, amount of pre-added pc and reaction time on pc synthesis were also examined. under the optimal reaction conditions, over 99% of pc yield was obtained. |
| WOS关键词 | CYCLIC CARBONATES ; DIOXIDE ; EPOXIDES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000278126200007 |
| 出版者 | SCIENCE PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2412170 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhou Xi |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou Xi,Yang Xiangui,Yao Jie,et al. Synthesis of propylene carbonate from co2 and propylene oxide with ki and inorganic ammonium salts as catalyst[J]. Acta chimica sinica,2010,68(9):870-874. |
| APA | Zhou Xi,Yang Xiangui,Yao Jie,&Wang Gongying.(2010).Synthesis of propylene carbonate from co2 and propylene oxide with ki and inorganic ammonium salts as catalyst.Acta chimica sinica,68(9),870-874. |
| MLA | Zhou Xi,et al."Synthesis of propylene carbonate from co2 and propylene oxide with ki and inorganic ammonium salts as catalyst".Acta chimica sinica 68.9(2010):870-874. |
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来源：中国科学院大学
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