A detailed study on the negative effect of residual sodium on the performance of ni/zno adsorbent for diesel fuel desulfurization
文献类型：期刊论文
| 作者 | Huang, Lichun1,2; Qin, Zhangfeng1; Wang, Guofu1; Du, Mingxian1; Ge, Hui1; Li, Xuekuan1; Wu, Zhiwei1,2; Wang, Jianguo1 |
| 刊名 | Industrial & engineering chemistry research
 |
| 出版日期 | 2010-05-19 |
| 卷号 | 49期号:10页码:4670-4675 |
| ISSN号 | 0888-5885 |
| DOI | 10.1021/ie100293h |
| 通讯作者 | Wang, jianguo(iccjgw@sxicc.ac.cn) |
| 英文摘要 | Desulfurization of diesel fuel was conducted via reactive adsorption over a coprecipitated ni/zno adsorbent. a negative effect of the residual sodium in ni/zno adsorbent on its adsorption performance was observed. the desulfurization ability of ni/zno adsorbent is markedly weakened with the increase in the residual sodium content. this negative effect can be attributed to the fact that the residual sodium decreases the adsorbent surface area and pore volume, suppresses the interaction between ni and zno, and leads to an increase in the crystallite size of the active species. moreover, the residual sodium is enriched on the adsorbent surface upon calcination and reduction treatment, which may promote the formation of the catalytically inactive ni-zn and nazn(oh)(3) species. |
| WOS关键词 | DEEP DESULFURIZATION ; REACTIVE ADSORPTION ; PI-COMPLEXATION ; CATALYST ; HYDROGEN ; THIOPHENE ; ZEOLITES ; HYDRODESULFURIZATION ; DECOMPOSITION ; CU/ZNO/AL2O3 |
| WOS研究方向 | Engineering |
| WOS类目 | Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000277443100022 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2412277 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang, Jianguo |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Lichun,Qin, Zhangfeng,Wang, Guofu,et al. A detailed study on the negative effect of residual sodium on the performance of ni/zno adsorbent for diesel fuel desulfurization[J]. Industrial & engineering chemistry research,2010,49(10):4670-4675. |
| APA | Huang, Lichun.,Qin, Zhangfeng.,Wang, Guofu.,Du, Mingxian.,Ge, Hui.,...&Wang, Jianguo.(2010).A detailed study on the negative effect of residual sodium on the performance of ni/zno adsorbent for diesel fuel desulfurization.Industrial & engineering chemistry research,49(10),4670-4675. |
| MLA | Huang, Lichun,et al."A detailed study on the negative effect of residual sodium on the performance of ni/zno adsorbent for diesel fuel desulfurization".Industrial & engineering chemistry research 49.10(2010):4670-4675. |
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来源：中国科学院大学
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