Copper(ii) complexes with n-(9-anthracenyl)-n '-(3-pyridyl)urea (l) and a derivative of l: synthesis, structure, and fluorescent properties
文献类型:期刊论文
作者 | Zhao, Qilong1,2; Yang, Xiao-Juan1; Jia, Chuandong1,2; Huang, Xiaojuan1; Wu, Biao1 |
刊名 | Zeitschrift fur anorganische und allgemeine chemie
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出版日期 | 2010-09-01 |
卷号 | 636期号:11页码:1998-2003 |
关键词 | N-(9-anthracenyl)-n '-(3-pyridyl)urea N-[10-(10-methoxy-anthronyl)]-n '-(3-pyridyl)urea Copper Fluorescence Supramolecular chemistry |
ISSN号 | 0044-2313 |
DOI | 10.1002/zaac.201000042 |
通讯作者 | Yang, xiao-juan(yangxj@lzb.ac.cn) |
英文摘要 | Three copper(ii) complexes, [cu(2)(oac)(4)l(2)].2ch(3)oh (1), [cubr(2)l(2)(1)(ch(3)oh)]center dot ch(3)oh (2a), and [cubr(2)l(2)(1)(dmso)]center dot 0.5ch(3)oh (2b) {l = n-(9-anthracenyl)-n'-(3-pyridyl) urea and l' = n-[10-(10-methoxy- anthronyl)]-n'-(3-pyridyl) urea} have been synthesized by the reaction of l with the corresponding copper(ii) salts. complex 1 shows a dinuclear structure with a conventional "paddlewheel" motif, in which four acetate units bridge the two cu(ii) ions. in complexes 2a and 2b, the anthracenyl ligand l has been converted to an anthronyl derivative l', and the central metal ion exhibits a distorted square pyramidal arrangement, with two pyridyl nitrogen atoms and two bromide ions defining the basal plane and the apical position is occupied by a solvent molecule (ch(3)oh in 2a and dmso in 2b). |
WOS关键词 | METAL-ORGANIC FRAMEWORKS ; HYDROGEN-BONDING GROUPS ; ANION-BINDING ; SUPRAMOLECULAR STRUCTURES ; LIGATING TOPOLOGIES ; COUNTER-ANIONS ; UREA ; COORDINATION ; ADSORPTION ; SEPARATION |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Inorganic & Nuclear |
语种 | 英语 |
WOS记录号 | WOS:000282743300018 |
出版者 | WILEY-BLACKWELL |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2413341 |
专题 | 中国科学院大学 |
通讯作者 | Yang, Xiao-Juan |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Qilong,Yang, Xiao-Juan,Jia, Chuandong,et al. Copper(ii) complexes with n-(9-anthracenyl)-n '-(3-pyridyl)urea (l) and a derivative of l: synthesis, structure, and fluorescent properties[J]. Zeitschrift fur anorganische und allgemeine chemie,2010,636(11):1998-2003. |
APA | Zhao, Qilong,Yang, Xiao-Juan,Jia, Chuandong,Huang, Xiaojuan,&Wu, Biao.(2010).Copper(ii) complexes with n-(9-anthracenyl)-n '-(3-pyridyl)urea (l) and a derivative of l: synthesis, structure, and fluorescent properties.Zeitschrift fur anorganische und allgemeine chemie,636(11),1998-2003. |
MLA | Zhao, Qilong,et al."Copper(ii) complexes with n-(9-anthracenyl)-n '-(3-pyridyl)urea (l) and a derivative of l: synthesis, structure, and fluorescent properties".Zeitschrift fur anorganische und allgemeine chemie 636.11(2010):1998-2003. |
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来源:中国科学院大学
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