Hydrated alkali metal halides as efficient catalysts for the synthesis of cyclic carbonates from co2 and epoxides
文献类型：期刊论文
| 作者 | Zhou Xi1,2; Zhang Yi1,2; Yang Xiangui1; Yao Jie1; Wang Gongying1 |
| 刊名 | Chinese journal of catalysis
 |
| 出版日期 | 2010-07-01 |
| 卷号 | 31期号:7页码:765-768 |
| 关键词 | Carbon dioxide Propylene oxide Propylene carbonate Cyclic carbonate Hydrated alkali metal halide |
| ISSN号 | 0253-9837 |
| DOI | 10.1016/s1872-2067(09)60086-3 |
| 通讯作者 | Zhou xi() |
| 英文摘要 | The synthesis of propylene carbonate from carbon dioxide and propylene oxide using hydrated alkali metal halides as catalysts in the absence of a co-catalyst and a solvent was investigated. the hydrated alkali metal halides showed much higher catalytic activity than the anhydrous alkali metal halides. sodium iodide dihydrate was found to be the most efficient among them and it gave a 97% yield of propylene carbonate at 120 degrees c under 1 mpa within 1.5 h. the corresponding cyclic carbonates from co2 and other epoxides using sodium iodide dihydrate as catalyst were also successfully synthesized. |
| WOS关键词 | ATMOSPHERIC-PRESSURE ; DIOXIDE ; MG |
| WOS研究方向 | Chemistry ; Engineering |
| WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000280868900008 |
| 出版者 | SCIENCE PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2413629 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhou Xi |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou Xi,Zhang Yi,Yang Xiangui,et al. Hydrated alkali metal halides as efficient catalysts for the synthesis of cyclic carbonates from co2 and epoxides[J]. Chinese journal of catalysis,2010,31(7):765-768. |
| APA | Zhou Xi,Zhang Yi,Yang Xiangui,Yao Jie,&Wang Gongying.(2010).Hydrated alkali metal halides as efficient catalysts for the synthesis of cyclic carbonates from co2 and epoxides.Chinese journal of catalysis,31(7),765-768. |
| MLA | Zhou Xi,et al."Hydrated alkali metal halides as efficient catalysts for the synthesis of cyclic carbonates from co2 and epoxides".Chinese journal of catalysis 31.7(2010):765-768. |
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来源：中国科学院大学
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