A novel effect of bis(6-heptenyl)zinc on the molecular weight and rheologic performance of polypropylene produced by rac-me2si[2-me-4-ph-ind](2)zrcl2/mao
文献类型：期刊论文
| 作者 | Zhang, Chuanhui1,2; Niu, Hui1; Dong, Jin-Yong1 |
| 刊名 | Polymer bulletin
 |
| 出版日期 | 2010-11-01 |
| 卷号 | 65期号:8页码:779-786 |
| 关键词 | Propylene polymerization Metallocene catalysts Alkylzinc compounds Copolymerization Chain transfer |
| ISSN号 | 0170-0839 |
| DOI | 10.1007/s00289-010-0245-6 |
| 通讯作者 | Zhang, chuanhui(zhangch@iccas.ac.cn) |
| 英文摘要 | The polymerization of propylene combined with bis(6-heptenyl)zinc (bhz) catalyzed by rac-me2si[2-me-4-ph-ind](2)zrcl2/mao was investigated. bhz acts as both a comonomer and a chain transfer reagent, which was verified by h-1 nmr and c-13 nmr spectra. a novel effect of bhz on the molecular weight and rheologic properties of the product was explained by the production of lcb. |
| WOS关键词 | POLYETHYLENE CHAIN GROWTH ; OLEFIN POLYMERIZATION CATALYSTS ; IMINE CHELATE LIGANDS ; PROPYLENE POLYMERIZATION ; PROPENE POLYMERIZATION ; FI CATALYSTS ; SHUTTLING POLYMERIZATION ; METALLOCENE CATALYSTS ; STEREOBLOCK POLYMERS ; BLOCK-COPOLYMERS |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000283508800003 |
| 出版者 | SPRINGER |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2414035 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhang, Chuanhui |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Chuanhui,Niu, Hui,Dong, Jin-Yong. A novel effect of bis(6-heptenyl)zinc on the molecular weight and rheologic performance of polypropylene produced by rac-me2si[2-me-4-ph-ind](2)zrcl2/mao[J]. Polymer bulletin,2010,65(8):779-786. |
| APA | Zhang, Chuanhui,Niu, Hui,&Dong, Jin-Yong.(2010).A novel effect of bis(6-heptenyl)zinc on the molecular weight and rheologic performance of polypropylene produced by rac-me2si[2-me-4-ph-ind](2)zrcl2/mao.Polymer bulletin,65(8),779-786. |
| MLA | Zhang, Chuanhui,et al."A novel effect of bis(6-heptenyl)zinc on the molecular weight and rheologic performance of polypropylene produced by rac-me2si[2-me-4-ph-ind](2)zrcl2/mao".Polymer bulletin 65.8(2010):779-786. |
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来源：中国科学院大学
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