Crystal structures and visible-light excited photoluminescence of n-methyl-4,4 '-bipyridinium chloride and its zn(ii) and cd(ii) complexes
文献类型：期刊论文
| 作者 | Yang, Chen1,2; Wang, Ming-Sheng1; Cai, Li-Zhen1; Jiang, Xiao-Ming1; Wu, Mei-Feng1; Guo, Guo-Cong1; Huang, Jin-Shun1 |
| 刊名 | Inorganic chemistry communications
 |
| 出版日期 | 2010-09-01 |
| 卷号 | 13期号:9页码:1021-1024 |
| 关键词 | Cationic ligand Group iib metal complex N-methyl-4,4 '-bipyridinium Photoluminescence Visible-light excitation |
| ISSN号 | 1387-7003 |
| DOI | 10.1016/j.inoche.2010.05.020 |
| 通讯作者 | Wang, ming-sheng(mswang@fjirsm.ac.cn) |
| 英文摘要 | A new approach has been used to synthesize mq(+) ligand (mq(+) = n-methyl-4,4'-bipyridinium) by the reaction of 4,4'-bipyridine and chloroacetic acid, and the structure of (mq)cl center dot h2o (1) was first determined. three new complexes containing mq(+), (mq)cdi3 (2). (mq)zni3 (3), and [(mq)zncl(1.53)i(1.47)](2)(mq) zncl1.68i1.32 (4). were successfully obtained via a solution or hydrothermal method by reaction of mi2 (m = cd, zn) with 1, and each of which exhibits an isolated structure, with each metal atom coordinated by one mq ligand and three terminal halogen atoms. compounds 1-4 all display photoluminescence in the visible region under visible-light excitation, and the origins of the emissions have been assigned to ilct for 1 and the combination of ilct and llct for 2-4. (c) 2010 elsevier b.v. all rights reserved. |
| WOS关键词 | RESONANCE RAMAN-SPECTROSCOPY ; HYDROTHERMAL SYNTHESIS ; RUTHENIUM(II) ; LIGANDS ; SYSTEMS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000281011900005 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2414584 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang, Ming-Sheng |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Chen,Wang, Ming-Sheng,Cai, Li-Zhen,et al. Crystal structures and visible-light excited photoluminescence of n-methyl-4,4 '-bipyridinium chloride and its zn(ii) and cd(ii) complexes[J]. Inorganic chemistry communications,2010,13(9):1021-1024. |
| APA | Yang, Chen.,Wang, Ming-Sheng.,Cai, Li-Zhen.,Jiang, Xiao-Ming.,Wu, Mei-Feng.,...&Huang, Jin-Shun.(2010).Crystal structures and visible-light excited photoluminescence of n-methyl-4,4 '-bipyridinium chloride and its zn(ii) and cd(ii) complexes.Inorganic chemistry communications,13(9),1021-1024. |
| MLA | Yang, Chen,et al."Crystal structures and visible-light excited photoluminescence of n-methyl-4,4 '-bipyridinium chloride and its zn(ii) and cd(ii) complexes".Inorganic chemistry communications 13.9(2010):1021-1024. |
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来源：中国科学院大学
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