One-step synthesis of li4ti5o12/c anode material with high performance for lithiumion batteries
文献类型:期刊论文
作者 | Lin, Ziji1,2; Hu, Xuebu3; Huai, Yongjian1,2; Liu, Li1,2,4; Deng, Zhenghua1,2,4; Suo, Jishuan1,2 |
刊名 | Solid state ionics
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出版日期 | 2010-03-29 |
卷号 | 181期号:8-10页码:412-415 |
关键词 | Spinel li4ti5o12 High-rate capability Polyacrylate Electric conductivity Lithium-ion batteries |
ISSN号 | 0167-2738 |
DOI | 10.1016/j.ssi.2010.01.019 |
通讯作者 | Deng, zhenghua(zhdeng@cioc.ac.cn) |
英文摘要 | Li4ti5o12/c anode material was simply obtained via a modified one-step solid-state reaction route using the original materials of lithium polyacrylate (paali) as lithium and carbon sources, and tio2 as titanium source. the physical characteristics of the li4ti5o12/c composite were investigated by x-ray diffraction, scanning electron microscopy and transmission electron microscopy techniques. the particle size of li4ti5o12 in the composite was about 200 nm. the electrochemical properties were evaluated by electrochemical impedance spectra and constant current charge/discharge cycling. it was demonstrated that the as-prepared li4ti5o12/c composite presented excellent high-rate characteristics and cycleabilities. the initial specific capacity of the composite was 130.0 ma h g(-1) at 8.60 ma cm(-2), and excellent cycle performance was still maintained with the current density increase. moreover, it was proved that the electric conductivity and cycle performance of li4ti5o12 were effectively enhanced due to the uniformly dispersed pyrolytic carbon in the li4ti5o12 particles. (c) 2010 elsevier b.v. all rights reserved. |
WOS关键词 | ALL-SOLID-STATE ; ELECTROCHEMICAL PROPERTIES ; ION BATTERIES ; NEGATIVE ELECTRODE ; SPINEL ; INSERTION ; CELLS |
WOS研究方向 | Chemistry ; Physics |
WOS类目 | Chemistry, Physical ; Physics, Condensed Matter |
语种 | 英语 |
WOS记录号 | WOS:000276781300007 |
出版者 | ELSEVIER SCIENCE BV |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2415219 |
专题 | 中国科学院大学 |
通讯作者 | Deng, Zhenghua |
作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Sichuan Normal Univ, Dept Chem & Mat, Chengdu 610068, Sichuan, Peoples R China 4.Zhongke Laifang Power Sci & Technol Co Ltd, Chengdu 610041, Sichuan, Peoples R China |
推荐引用方式 GB/T 7714 | Lin, Ziji,Hu, Xuebu,Huai, Yongjian,et al. One-step synthesis of li4ti5o12/c anode material with high performance for lithiumion batteries[J]. Solid state ionics,2010,181(8-10):412-415. |
APA | Lin, Ziji,Hu, Xuebu,Huai, Yongjian,Liu, Li,Deng, Zhenghua,&Suo, Jishuan.(2010).One-step synthesis of li4ti5o12/c anode material with high performance for lithiumion batteries.Solid state ionics,181(8-10),412-415. |
MLA | Lin, Ziji,et al."One-step synthesis of li4ti5o12/c anode material with high performance for lithiumion batteries".Solid state ionics 181.8-10(2010):412-415. |
入库方式: iSwitch采集
来源:中国科学院大学
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