中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
One-step synthesis of li4ti5o12/c anode material with high performance for lithiumion batteries

文献类型:期刊论文

作者Lin, Ziji1,2; Hu, Xuebu3; Huai, Yongjian1,2; Liu, Li1,2,4; Deng, Zhenghua1,2,4; Suo, Jishuan1,2
刊名Solid state ionics
出版日期2010-03-29
卷号181期号:8-10页码:412-415
关键词Spinel li4ti5o12 High-rate capability Polyacrylate Electric conductivity Lithium-ion batteries
ISSN号0167-2738
DOI10.1016/j.ssi.2010.01.019
通讯作者Deng, zhenghua(zhdeng@cioc.ac.cn)
英文摘要Li4ti5o12/c anode material was simply obtained via a modified one-step solid-state reaction route using the original materials of lithium polyacrylate (paali) as lithium and carbon sources, and tio2 as titanium source. the physical characteristics of the li4ti5o12/c composite were investigated by x-ray diffraction, scanning electron microscopy and transmission electron microscopy techniques. the particle size of li4ti5o12 in the composite was about 200 nm. the electrochemical properties were evaluated by electrochemical impedance spectra and constant current charge/discharge cycling. it was demonstrated that the as-prepared li4ti5o12/c composite presented excellent high-rate characteristics and cycleabilities. the initial specific capacity of the composite was 130.0 ma h g(-1) at 8.60 ma cm(-2), and excellent cycle performance was still maintained with the current density increase. moreover, it was proved that the electric conductivity and cycle performance of li4ti5o12 were effectively enhanced due to the uniformly dispersed pyrolytic carbon in the li4ti5o12 particles. (c) 2010 elsevier b.v. all rights reserved.
WOS关键词ALL-SOLID-STATE ; ELECTROCHEMICAL PROPERTIES ; ION BATTERIES ; NEGATIVE ELECTRODE ; SPINEL ; INSERTION ; CELLS
WOS研究方向Chemistry ; Physics
WOS类目Chemistry, Physical ; Physics, Condensed Matter
语种英语
WOS记录号WOS:000276781300007
出版者ELSEVIER SCIENCE BV
URI标识http://www.irgrid.ac.cn/handle/1471x/2415219
专题中国科学院大学
通讯作者Deng, Zhenghua
作者单位1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
3.Sichuan Normal Univ, Dept Chem & Mat, Chengdu 610068, Sichuan, Peoples R China
4.Zhongke Laifang Power Sci & Technol Co Ltd, Chengdu 610041, Sichuan, Peoples R China
推荐引用方式
GB/T 7714
Lin, Ziji,Hu, Xuebu,Huai, Yongjian,et al. One-step synthesis of li4ti5o12/c anode material with high performance for lithiumion batteries[J]. Solid state ionics,2010,181(8-10):412-415.
APA Lin, Ziji,Hu, Xuebu,Huai, Yongjian,Liu, Li,Deng, Zhenghua,&Suo, Jishuan.(2010).One-step synthesis of li4ti5o12/c anode material with high performance for lithiumion batteries.Solid state ionics,181(8-10),412-415.
MLA Lin, Ziji,et al."One-step synthesis of li4ti5o12/c anode material with high performance for lithiumion batteries".Solid state ionics 181.8-10(2010):412-415.

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来源:中国科学院大学

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