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Chinese Academy of Sciences Institutional Repositories Grid
Polymer-assisted isolation of single wall carbon nanotubes in organic solvents for optical-quality nanotube-polymer composites

文献类型:期刊论文

作者Hasan, T.1; Tan, P. H.1,2; Bonaccorso, F.1,3,4; Rozhin, A. G.1; Scardaci, V.1; Milne, W. I.1; Ferrari, A. C.1
刊名Journal of physical chemistry c
出版日期2008-12-25
卷号112期号:51页码:20227-20232
ISSN号1932-7447
DOI10.1021/jp807036w
通讯作者Hasan, t.()
英文摘要Dispersions of isolated single wall carbon nanotubes (swnts) in pure organic solvents can usually be prepared only at low concentrations (similar to 0.01-0.02 g/l). here, we use poly(vinylpyrrolidone) as a dispersant for unfunctionalized swnts in n-methyl-2-pyrrolidone and achieve concentrations of up to similar to 0.16 g/l. such dispersions remain stable by visual inspection for at least 1 year after preparation. well-resolved features in the absorption spectra are observed, implying the presence of isolated swnts or small bundles. this is further confirmed by photoluminescence excitation spectroscopy. dispersions enriched with isolated swnts are obtained by ultracentrifugation. strong photoluminescence signal from nanotubes with similar to 1 nm diameter indicates the dispersion mechanism to be diameter selective. swnt-polymer composites prepared from filtered dispersions, with styrene methyl methacrylate (smma) as host matrix, are obtained with sub-micrometer aggregations and high optical density. the high transparency of smma below 1650 nm is promising when such swnt-polymer composites are to be used in telecommunication applications.
WOS关键词NONCOVALENT INTERACTIONS ; ABSORPTION-SPECTROSCOPY ; AMIDE SOLVENTS ; DISPERSION ; BUNDLES ; FUNCTIONALIZATION ; SOLUBILIZATION ; SURFACTANTS ; DISSOLUTION ; DEPENDENCE
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
语种英语
WOS记录号WOS:000261835000023
出版者AMER CHEMICAL SOC
URI标识http://www.irgrid.ac.cn/handle/1471x/2427461
专题半导体研究所
通讯作者Hasan, T.
作者单位1.Univ Cambridge, Dept Engn, Cambridge CB3 0FA, England
2.State Key Lab Superlattices & Microstruct, Beijing 100083, Peoples R China
3.Univ Messina, CNR, IPCF, Messina, Italy
4.Univ Messina, Dipartimento Fis Mat & Ingn Elettron, Messina, Italy
推荐引用方式
GB/T 7714
Hasan, T.,Tan, P. H.,Bonaccorso, F.,et al. Polymer-assisted isolation of single wall carbon nanotubes in organic solvents for optical-quality nanotube-polymer composites[J]. Journal of physical chemistry c,2008,112(51):20227-20232.
APA Hasan, T..,Tan, P. H..,Bonaccorso, F..,Rozhin, A. G..,Scardaci, V..,...&Ferrari, A. C..(2008).Polymer-assisted isolation of single wall carbon nanotubes in organic solvents for optical-quality nanotube-polymer composites.Journal of physical chemistry c,112(51),20227-20232.
MLA Hasan, T.,et al."Polymer-assisted isolation of single wall carbon nanotubes in organic solvents for optical-quality nanotube-polymer composites".Journal of physical chemistry c 112.51(2008):20227-20232.

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来源:半导体研究所

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