Polymer-assisted isolation of single wall carbon nanotubes in organic solvents for optical-quality nanotube-polymer composites
文献类型:期刊论文
作者 | Hasan, T.1; Tan, P. H.1,2; Bonaccorso, F.1,3,4; Rozhin, A. G.1; Scardaci, V.1; Milne, W. I.1; Ferrari, A. C.1 |
刊名 | Journal of physical chemistry c
![]() |
出版日期 | 2008-12-25 |
卷号 | 112期号:51页码:20227-20232 |
ISSN号 | 1932-7447 |
DOI | 10.1021/jp807036w |
通讯作者 | Hasan, t.() |
英文摘要 | Dispersions of isolated single wall carbon nanotubes (swnts) in pure organic solvents can usually be prepared only at low concentrations (similar to 0.01-0.02 g/l). here, we use poly(vinylpyrrolidone) as a dispersant for unfunctionalized swnts in n-methyl-2-pyrrolidone and achieve concentrations of up to similar to 0.16 g/l. such dispersions remain stable by visual inspection for at least 1 year after preparation. well-resolved features in the absorption spectra are observed, implying the presence of isolated swnts or small bundles. this is further confirmed by photoluminescence excitation spectroscopy. dispersions enriched with isolated swnts are obtained by ultracentrifugation. strong photoluminescence signal from nanotubes with similar to 1 nm diameter indicates the dispersion mechanism to be diameter selective. swnt-polymer composites prepared from filtered dispersions, with styrene methyl methacrylate (smma) as host matrix, are obtained with sub-micrometer aggregations and high optical density. the high transparency of smma below 1650 nm is promising when such swnt-polymer composites are to be used in telecommunication applications. |
WOS关键词 | NONCOVALENT INTERACTIONS ; ABSORPTION-SPECTROSCOPY ; AMIDE SOLVENTS ; DISPERSION ; BUNDLES ; FUNCTIONALIZATION ; SOLUBILIZATION ; SURFACTANTS ; DISSOLUTION ; DEPENDENCE |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
WOS类目 | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000261835000023 |
出版者 | AMER CHEMICAL SOC |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2427461 |
专题 | 半导体研究所 |
通讯作者 | Hasan, T. |
作者单位 | 1.Univ Cambridge, Dept Engn, Cambridge CB3 0FA, England 2.State Key Lab Superlattices & Microstruct, Beijing 100083, Peoples R China 3.Univ Messina, CNR, IPCF, Messina, Italy 4.Univ Messina, Dipartimento Fis Mat & Ingn Elettron, Messina, Italy |
推荐引用方式 GB/T 7714 | Hasan, T.,Tan, P. H.,Bonaccorso, F.,et al. Polymer-assisted isolation of single wall carbon nanotubes in organic solvents for optical-quality nanotube-polymer composites[J]. Journal of physical chemistry c,2008,112(51):20227-20232. |
APA | Hasan, T..,Tan, P. H..,Bonaccorso, F..,Rozhin, A. G..,Scardaci, V..,...&Ferrari, A. C..(2008).Polymer-assisted isolation of single wall carbon nanotubes in organic solvents for optical-quality nanotube-polymer composites.Journal of physical chemistry c,112(51),20227-20232. |
MLA | Hasan, T.,et al."Polymer-assisted isolation of single wall carbon nanotubes in organic solvents for optical-quality nanotube-polymer composites".Journal of physical chemistry c 112.51(2008):20227-20232. |
入库方式: iSwitch采集
来源:半导体研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。