Mass Spectrometric Identification of Aliphatic Amines Using 2-[2-(7H-dibenzo[a,g]-carbazol-7-yl)-ethoxy] ethyl Chloroformate as Novel Fluorescence Labeling Reagent
文献类型：期刊论文
| 作者 | Yan Tao1; Sun Xue-Jun1; Zhao Huai-Xin1; Sun Zhi-Wei1; Liu Qin-Ze1; Suo You-Rui2; You Jin-Mao1,2 |
| 刊名 | chinese journal of analytical chemistry
 |
| 出版日期 | 2009-06-01 |
| 卷号 | 37期号:6页码:788-794 |
| 关键词 | High performance liquid chromatography/ion-trap mass spectrometry fluorescence detection precolumn derivatization aliphatic amines 2-[2-(7H-dibenzo[a,g] carbazol-7-yl)-ethoxy] ethyl chloroformate |
| ISSN号 | 0253-3820 |
| 中文摘要 | on a reversed-phase eclipse xdb c8 ( 150 mm x 4.6 mm, 5 mu m) column, 12 aliphatic amine derivatives were derivatized using 2-[2-(7h-dibenzo[a, g] carbazol-7-yl)-ethoxy] ethyl chloroformate (dbcec-cl) as a new pre-column derivatization reagent. the complete baseline resolution was obtained in conjunction with a gradient elution with acetonitrile/h(2)o as mobile phase. detection was carried out by the fluorescence and online post-column atmospheric pressure chemical ionization(apci) in positive-ion mode. the maximum excitation and emission wavelengths were at 300 nm and 400 nm, respectively. identification of aliphatic amine derivatives was carried out by the online post-column ion trap/mass spectrometry with positive-ion detection mode of apci-ms. a rapid, accurate method for the determination of free aliphatic amine extracted from soil was proposed. the established method exhibited excellent reproducibility and recovery. excellent linear responses were observed with the correlation coefficients > 0.9991. the detection limits( at signal-to-noise of 3:1) were 10.1-0.3 fmol. |
| 英文摘要 | on a reversed-phase eclipse xdb c8 ( 150 mm x 4.6 mm, 5 mu m) column, 12 aliphatic amine derivatives were derivatized using 2-[2-(7h-dibenzo[a, g] carbazol-7-yl)-ethoxy] ethyl chloroformate (dbcec-cl) as a new pre-column derivatization reagent. the complete baseline resolution was obtained in conjunction with a gradient elution with acetonitrile/h(2)o as mobile phase. detection was carried out by the fluorescence and online post-column atmospheric pressure chemical ionization(apci) in positive-ion mode. the maximum excitation and emission wavelengths were at 300 nm and 400 nm, respectively. identification of aliphatic amine derivatives was carried out by the online post-column ion trap/mass spectrometry with positive-ion detection mode of apci-ms. a rapid, accurate method for the determination of free aliphatic amine extracted from soil was proposed. the established method exhibited excellent reproducibility and recovery. excellent linear responses were observed with the correlation coefficients > 0.9991. the detection limits( at signal-to-noise of 3:1) were 10.1-0.3 fmol. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | performance liquid-chromatography ; precolumn derivatization ; 6-aminoquinolyl-n-hydroxysuccinimidyl carbamate ; ortho-phthaldialdehyde ; acids ; hydrolysate |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000267385100002 |
| 公开日期 | 2011-12-13 |
| 源URL | [http://ir.nwipb.ac.cn//handle/363003/1864]  |
| 专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
| 作者单位 | 1.Qufu Normal Univ, Shandong Key Lab Life Organ Anal, Coll Chem Sci, Qufu 273165, Peoples R China 2.Chinese Acad Sci, NW Plateau Inst Biol, Xining 810001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yan Tao,Sun Xue-Jun,Zhao Huai-Xin,et al. Mass Spectrometric Identification of Aliphatic Amines Using 2-[2-(7H-dibenzo[a,g]-carbazol-7-yl)-ethoxy] ethyl Chloroformate as Novel Fluorescence Labeling Reagent[J]. chinese journal of analytical chemistry,2009,37(6):788-794. |
| APA | Yan Tao.,Sun Xue-Jun.,Zhao Huai-Xin.,Sun Zhi-Wei.,Liu Qin-Ze.,...&You Jin-Mao.(2009).Mass Spectrometric Identification of Aliphatic Amines Using 2-[2-(7H-dibenzo[a,g]-carbazol-7-yl)-ethoxy] ethyl Chloroformate as Novel Fluorescence Labeling Reagent.chinese journal of analytical chemistry,37(6),788-794. |
| MLA | Yan Tao,et al."Mass Spectrometric Identification of Aliphatic Amines Using 2-[2-(7H-dibenzo[a,g]-carbazol-7-yl)-ethoxy] ethyl Chloroformate as Novel Fluorescence Labeling Reagent".chinese journal of analytical chemistry 37.6(2009):788-794. |
入库方式： OAI收割
来源：西北高原生物研究所
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