Selective cleavage of lignin and lignin model compounds without external hydrogen, catalyzed by heterogeneous nickel catalysts
文献类型：期刊论文
| 作者 | Jiang, Liang2; Guo, Haiwei1,3; Li, Changzhi3; Zhou, Peng2; Zhang, Zehui2 |
| 刊名 | CHEMICAL SCIENCE
 |
| 出版日期 | 2019-04-28 |
| 卷号 | 10期号:16页码:4458-4468 |
| ISSN号 | 2041-6520 |
| DOI | 10.1039/c9sc00691e |
| 通讯作者 | Li, Changzhi(licz@dicp.ac.cn) ; Zhang, Zehui(zehuizh@mail.ustc.edu.cn) |
| 英文摘要 | Selective hydrogenolysis of the C-aryl-O bonds in lignin is a key strategy for the generation of fuels and chemical feedstocks from biomass. Currently, hydrogenolysis has been mainly conducted using hydrogen, which is flammable and not sustainable or economical. Herein, an external hydrogen-free process for aryl ethers hydrogenolysis in lignin models and dioxasolv lignin over nickel nanoparticles supported on Al2O3, is reported. Kinetic studies reveal that the transfer hydrogenolysis activity of the three model compounds decreased in the following order: benzyl phenyl ether (a-O-4), 2-phenylethyl phenyl ether (b-O-4) and diphenyl ether (4-O-5), which linearly corresponds to their binding energies and the activation energies. The main reaction route for the three model compounds was the cleavage of the ether bonds to produce aromatic alkanes and phenol, and the latter was further reduced to cyclohexanol. Dioxasolv lignin depolymerization results exhibit a significant Caryl-O decrease over the Ni nanoparticles supported on Al2O3 with iso-propanol as the hydrogen source through 2D-HSQC-NMR analysis, which confirmed the transfer hydrogenolysis conclusion in the model study. This work provides an economical and environmentally-friendly method for the selective cleavage of lignin and lignin model compounds into value-added chemicals. |
| WOS关键词 | O BOND-CLEAVAGE ; RANEY(R) NI ; ARYL ETHERS ; BIO-OIL ; BIOMASS ; DEPOLYMERIZATION ; OXIDATION ; 2,5-DIFORMYLFURAN ; NANOPARTICLES |
| 资助项目 | Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities[CZR18001] ; Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities[YCZW15100] ; Natural Science Foundation of Hubei Province[2017CFB432] ; National Natural Science Foundation of China[21872175] ; National Natural Science Foundation of China[21690080] ; National Natural Science Foundation of China[21690083] ; National Natural Science Foundation of China[21878288] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000465341000007 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities ; Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities ; Natural Science Foundation of Hubei Province ; Natural Science Foundation of Hubei Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities ; Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities ; Natural Science Foundation of Hubei Province ; Natural Science Foundation of Hubei Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities ; Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities ; Natural Science Foundation of Hubei Province ; Natural Science Foundation of Hubei Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities ; Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities ; Natural Science Foundation of Hubei Province ; Natural Science Foundation of Hubei Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/165528]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Changzhi; Zhang, Zehui |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.South Cent Univ Nationalities, Key Lab Catalysis & Mat Sci, Minist Educ, Wuhan 430074, Hubei, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Liang,Guo, Haiwei,Li, Changzhi,et al. Selective cleavage of lignin and lignin model compounds without external hydrogen, catalyzed by heterogeneous nickel catalysts[J]. CHEMICAL SCIENCE,2019,10(16):4458-4468. |
| APA | Jiang, Liang,Guo, Haiwei,Li, Changzhi,Zhou, Peng,&Zhang, Zehui.(2019).Selective cleavage of lignin and lignin model compounds without external hydrogen, catalyzed by heterogeneous nickel catalysts.CHEMICAL SCIENCE,10(16),4458-4468. |
| MLA | Jiang, Liang,et al."Selective cleavage of lignin and lignin model compounds without external hydrogen, catalyzed by heterogeneous nickel catalysts".CHEMICAL SCIENCE 10.16(2019):4458-4468. |
入库方式： OAI收割
来源：大连化学物理研究所
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