Fast fabrication of a hybrid monolithic column containing cyclic and aliphatic hydrophobic ligands via photo-initiated thiol-ene polymerization
文献类型：期刊论文
| 作者 | Wang, Yan1,2; Ma, Shujuan1,2; Zhang, Luwei1,2; Zhang, Na2,3; Li, Yanan2,3; Ou, Junjie2; Shen, Yehua1; Ye, Mingliang2 |
| 刊名 | JOURNAL OF SEPARATION SCIENCE
 |
| 出版日期 | 2019-04-01 |
| 卷号 | 42期号:7页码:1332-1340 |
| 关键词 | capillary liquid chromatography click chemistry hybrid monolithic column |
| ISSN号 | 1615-9306 |
| DOI | 10.1002/jssc.201801033 |
| 通讯作者 | Ou, Junjie(junjieou@dicp.ac.cn) ; Shen, Yehua(yhshen@nwu.edu.cn) |
| 英文摘要 | Three monomers, octakis (3-mercaptopropyl) octasilsesquioxane, 1,2,4-trivinylcyclohexane and isophytol were employed to synthesize a novel monolithic stationary phase via photo-initiated thiol-ene click polymerization for reversed-phase liquid chromatography. Several factors such as porogenic system, reaction time and the molar ratio of functional groups were investigated in detail. The resulting poly(POSS-co-TVCH-co-isophytol) monolithic column exhibited suitable permeability for fast separation and outstanding thermal stability. Five alkylbenzenes were employed to evaluate the ability of chromatographic separation of the resulting monolithic columns at different flow rates, and showed the highest column efficiencies of 90,200-93,100 N/m (corresponding to 10.4-10.6 mu m of plate height) at a velocity of 0.41 mm/s. The baseline separations of five anilines and eight phenols further proved the applicability of poly(POSS-co-TVCH-co-isophytol) monolithic column in the separation of small molecules. |
| WOS关键词 | POLYHEDRAL OLIGOMERIC SILSESQUIOXANE ; RING-OPENING POLYMERIZATION ; CLICK CHEMISTRY ; PHOTOPOLYMERIZATION ; PERFORMANCE ; IMPACT |
| 资助项目 | China State Key Basic Research Program Grant[2016YFA0501402] ; National Science Fund for Distinguished Young Scholars[21525524] ; National Natural Sciences Foundation of China[21575141] ; CAS Weigao Research & Development Program[[2017]-009] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000466423100004 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS Weigao Research & Development Program ; CAS Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS Weigao Research & Development Program ; CAS Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS Weigao Research & Development Program ; CAS Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS Weigao Research & Development Program ; CAS Weigao Research & Development Program |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/165534]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Ou, Junjie; Shen, Yehua |
| 作者单位 | 1.Northwest Univ, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Xian, Shaanxi, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yan,Ma, Shujuan,Zhang, Luwei,et al. Fast fabrication of a hybrid monolithic column containing cyclic and aliphatic hydrophobic ligands via photo-initiated thiol-ene polymerization[J]. JOURNAL OF SEPARATION SCIENCE,2019,42(7):1332-1340. |
| APA | Wang, Yan.,Ma, Shujuan.,Zhang, Luwei.,Zhang, Na.,Li, Yanan.,...&Ye, Mingliang.(2019).Fast fabrication of a hybrid monolithic column containing cyclic and aliphatic hydrophobic ligands via photo-initiated thiol-ene polymerization.JOURNAL OF SEPARATION SCIENCE,42(7),1332-1340. |
| MLA | Wang, Yan,et al."Fast fabrication of a hybrid monolithic column containing cyclic and aliphatic hydrophobic ligands via photo-initiated thiol-ene polymerization".JOURNAL OF SEPARATION SCIENCE 42.7(2019):1332-1340. |
入库方式： OAI收割
来源：大连化学物理研究所
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