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Catalytic selective hydrogenation and rearrangement of 5-hydroxymethylfurfural to 3-hydroxymethyl-cyclopentone over a bimetallic nickel-copper catalyst in water

文献类型：期刊论文

作者Gao, Jin1; Zhang, Shujing1,2; Ma, Hong1; Sun, Yuxia1,2; Luo, Yang1,2; Liu, Xin1,2; Zhang, Meiyun1,2; Xu, Jie1
刊名GREEN CHEMISTRY
出版日期2019-04-07
卷号21期号:7页码:1702-1709
ISSN号1463-9262
DOI10.1039/c8gc04009e
通讯作者Ma, Hong(mahong@dicp.ac.cn) ; Xu, Jie(xujie@dicp.ac.cn)
英文摘要The selective hydrogenation and rearrangement of 5-hydroxymethylfurfural (5-HMF) to 3-hydroxymethyl-cyclopentone (HCPN) were studied over a MOF-derived bimetallic nickel-copper catalyst in water. The combination of nickel and copper dramatically improved the efficiency in both the selective hydrogenation of the carbonyl group of 5-HMF and the hydrogenative ring-rearrangement of the C5 ring, affording 70.3% yield for HCPN and 99.8% yield for the rearrangement products. Moreover, it was indicated that water acted as a solvent, reactant, and proton donor by dissociation at an elevated temperature, which supplied slightly acidic conditions and promoted the rearrangement reaction.
WOS关键词AEROBIC OXIDATION ; RING-REARRANGEMENT ; CONVERSION ; CARBON ; HYDROGENOLYSIS ; CYCLOPENTANONE ; FRUCTOSE ; COBALT ; HMF ; 2,5-HEXANEDIONE
资助项目National Natural Science Foundation of China[21790331] ; National Natural Science Foundation of China[21872138] ; National Natural Science Foundation of China[21690084] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21030400] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020300]
WOS研究方向Chemistry ; Science & Technology - Other Topics
语种英语
WOS记录号WOS:000464318800012
出版者ROYAL SOC CHEMISTRY
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences
源URL[http://cas-ir.dicp.ac.cn/handle/321008/165542]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Ma, Hong; Xu, Jie
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714		 Gao, Jin,Zhang, Shujing,Ma, Hong,et al. Catalytic selective hydrogenation and rearrangement of 5-hydroxymethylfurfural to 3-hydroxymethyl-cyclopentone over a bimetallic nickel-copper catalyst in water[J]. GREEN CHEMISTRY,2019,21(7):1702-1709.
APA Gao, Jin.,Zhang, Shujing.,Ma, Hong.,Sun, Yuxia.,Luo, Yang.,...&Xu, Jie.(2019).Catalytic selective hydrogenation and rearrangement of 5-hydroxymethylfurfural to 3-hydroxymethyl-cyclopentone over a bimetallic nickel-copper catalyst in water.GREEN CHEMISTRY,21(7),1702-1709.
MLA Gao, Jin,et al."Catalytic selective hydrogenation and rearrangement of 5-hydroxymethylfurfural to 3-hydroxymethyl-cyclopentone over a bimetallic nickel-copper catalyst in water".GREEN CHEMISTRY 21.7(2019):1702-1709.

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来源：大连化学物理研究所

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