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Selective photoelectrochemical oxidation of glycerol to high value-added dihydroxyacetone

文献类型：期刊论文

作者Yang, Hong Bin3,4; Liu, Dong4; Liu, Jin-Cheng5,6; Cai, Weizheng4; Ma, Jun2; Xiao, Hai5,6; Li, Jun5,6; Xiong, Yujie2; Huang, Yanqiang1; Liu, Bin4
刊名NATURE COMMUNICATIONS
出版日期2019-04-16
卷号10页码:8
ISSN号2041-1723
DOI10.1038/s41467-019-09788-5
通讯作者Xiao, Hai(haixiao@tsinghua.edu.cn) ; Xiong, Yujie(yjxiong@ustc.edu.cn) ; Liu, Bin(liubin@ntu.edu.sg)
英文摘要It is highly profitable to transform glycerol - the main by-product from biodiesel production to high value-added chemicals. In this work, we develop a photoelectrochemical system based on nanoporous BiVO4 for selective oxidation of glycerol to 1,3-dihydroxyacetone - one of the most valuable derivatives of glycerol. Under AM 1.5G front illumination (100 mW cm(-2)) in an acidic medium (pH = 2) without adscititious oxidant, the nanoporous BiVO4 photoanode achieves a glycerol oxidation photocurrent density of 3.7 mA cm(-2) at a potential of 1.2 V versus RHE with 51% 1,3-dihydroxyacetone selectivity, equivalent to a production rate of 200 mmol of 1,3-dihydroxyacetone per m(2) of illumination area in one hour.
WOS关键词TOTAL-ENERGY CALCULATIONS ; ELECTROCATALYTIC OXIDATION ; WATER OXIDATION ; ELECTROOXIDATION ; BIODIESEL ; CATALYSTS ; CONVERSION ; CHEMICALS ; PLATINUM ; MECHANISM
资助项目Singapore Ministry of Education[RG115/18] ; Singapore Ministry of Education[RG115/17] ; Singapore Ministry of Education[RG9/17] ; Singapore Ministry of Education[MOE2016-T2-2-004] ; National Key Projects for Fundamental Research and Development of China[2017YFA0207301] ; National Key Projects for Fundamental Research and Development of China[2016YFA0202804] ; Strategic Priority Research Programme of the Chinese Academy of Sciences[XDB17020400] ; National Nature Science Foundation of China[21725102]
WOS研究方向Science & Technology - Other Topics
语种英语
WOS记录号WOS:000464654700018
出版者NATURE PUBLISHING GROUP
资助机构Singapore Ministry of Education ; Singapore Ministry of Education ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Singapore Ministry of Education ; Singapore Ministry of Education ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Singapore Ministry of Education ; Singapore Ministry of Education ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Singapore Ministry of Education ; Singapore Ministry of Education ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; National Nature Science Foundation of China ; National Nature Science Foundation of China
源URL[http://cas-ir.dicp.ac.cn/handle/321008/165574]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Xiao, Hai; Xiong, Yujie; Liu, Bin
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Sch Chem & Mat Sci, Collaborat Innovat Ctr Chem Energy Mat iChEM, Hefei 230026, Anhui, Peoples R China
3.Suzhou Univ Sci & Technol, Inst Mat Sci & Devices, Suzhou 215009, Peoples R China
4.Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr, Singapore 637459, Singapore
5.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
6.Tsinghua Univ, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China
推荐引用方式
GB/T 7714		 Yang, Hong Bin,Liu, Dong,Liu, Jin-Cheng,et al. Selective photoelectrochemical oxidation of glycerol to high value-added dihydroxyacetone[J]. NATURE COMMUNICATIONS,2019,10:8.
APA Yang, Hong Bin.,Liu, Dong.,Liu, Jin-Cheng.,Cai, Weizheng.,Ma, Jun.,...&Liu, Bin.(2019).Selective photoelectrochemical oxidation of glycerol to high value-added dihydroxyacetone.NATURE COMMUNICATIONS,10,8.
MLA Yang, Hong Bin,et al."Selective photoelectrochemical oxidation of glycerol to high value-added dihydroxyacetone".NATURE COMMUNICATIONS 10(2019):8.

入库方式： OAI收割

来源：大连化学物理研究所

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