One-step preparation of phosphate-rich carbonaceous spheres via a hydrothermal approach for phosphopeptide analysis
文献类型：期刊论文
| 作者 | Li, Xiaowei1,3; Ma, Shujuan1,2; Ou, Junjie1,3; Wei, Yinmao2; Ye, Mingliang1,3; Zhang, Haiyang1,2 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2019-04-21 |
| 卷号 | 21期号:8页码:2052-2060 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c8gc03706j |
| 通讯作者 | Ou, Junjie(junjieou@dicp.ac.cn) ; Wei, Yinmao(ymwei@nwu.edu.cn) |
| 英文摘要 | Carbonaceous materials with different morphologies are attracting more and more attention in many fields due to their excellent performance. Various methods have been developed to prepare carbonaceous materials with different functions. In this work, we developed a green strategy to prepare phosphate-rich carbonaceous spheres via a one-step mild hydrothermal carbonization (HTC) process using glucose and vinylphosphonic acid (VPA) as precursors. Water was the sole solvent employed in this synthesis process, which is environmentally friendly. To augment the content of phosphate groups on the surfaces of carbonaceous spheres, water-soluble 4,4-azobis(4-cyanovaleric acid) was added to the HTC system as a thermal initiator. The size of the obtained carbonaceous spheres could reach 1-8 m. Following chelation with titanium ions (Ti4+), the carbonaceous spheres were applied as an immobilized metal affinity chromatography (IMAC) material; the Ti4+ content of carbonaceous spheres reached 2.685% (wt%). This synthetic process for Ti4+-IMAC carbonaceous spheres was facile and time-saving, avoiding the tedious and complex process for traditional Ti4+-IMAC materials. Furthermore, the Ti4+-IMAC carbonaceous spheres exhibited satisfactory enrichment ability for phosphopeptides in the digest of -casein and could enrich the low-abundance phosphopeptides in human serum, indicating a great potential use in phosphopeptide analysis. |
| WOS关键词 | HIGHLY SELECTIVE ENRICHMENT ; METAL-ORGANIC FRAMEWORK ; PHOSPHORYLATED PEPTIDES ; MONOLITHIC CAPILLARY ; FACILE PREPARATION ; MASS-SPECTROMETRY ; ENERGY-STORAGE ; IN-VIVO ; CARBONIZATION ; TITANIUM |
| 资助项目 | China State Key Basic Research Program Grant[2016YFA0501402] ; National Science Fund for Distinguished Young Scholars[21525524] ; National Natural Sciences Foundation of China[21575141] ; CAS-Weigao Research & Development Program[[2017]-009] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000465398000020 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/165598]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Ou, Junjie; Wei, Yinmao |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Separat Sci Analyt Chem, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Northwest Univ, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Coll Chem & Mat Sci, Xian 710069, Shaanxi, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xiaowei,Ma, Shujuan,Ou, Junjie,et al. One-step preparation of phosphate-rich carbonaceous spheres via a hydrothermal approach for phosphopeptide analysis[J]. GREEN CHEMISTRY,2019,21(8):2052-2060. |
| APA | Li, Xiaowei,Ma, Shujuan,Ou, Junjie,Wei, Yinmao,Ye, Mingliang,&Zhang, Haiyang.(2019).One-step preparation of phosphate-rich carbonaceous spheres via a hydrothermal approach for phosphopeptide analysis.GREEN CHEMISTRY,21(8),2052-2060. |
| MLA | Li, Xiaowei,et al."One-step preparation of phosphate-rich carbonaceous spheres via a hydrothermal approach for phosphopeptide analysis".GREEN CHEMISTRY 21.8(2019):2052-2060. |
入库方式： OAI收割
来源：大连化学物理研究所
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