Charge Transfer Reactions in CO2 Electroreduction on Manganese Doped Ceria
文献类型：期刊论文
| 作者 | Yang, Weishen1; Cheng, Mojie2; Huang, Zhidong2,3; Shang, Lei2,3; Qi, Huiying2,3; Zhao, Zhe2; Tu, Baofeng2 |
| 刊名 | CHEMELECTROCHEM
 |
| 出版日期 | 2019-03-15 |
| 卷号 | 6期号:6页码:1668-1672 |
| 关键词 | carbon dioxide reduction electrocatalysis heterogeneous catalysis solid oxide electrolysis cell surface chemistry |
| ISSN号 | 2196-0216 |
| DOI | 10.1002/celc.201801427 |
| 通讯作者 | Cheng, Mojie(mjcheng@dicp.ac.cn) |
| 英文摘要 | The key to electrochemical conversion of carbon dioxide (CO2) into fuels lies in effient charge transfer reactions. Here, we depict from the polarzation resistance analysis that the electroreduction of CO2 to CO on manganese doped ceria (CMO) passes through two elementary charge transfer reactions. One reaction is asscociated with (CO3)(O,S)(center dot) to (CO3)(O,S)(center dot) and another associated with (CO3)(O,S)(center dot). O; S to CO. As the rate determing step, the first one has an apparenent acitvation energy of 178.7 kJ mol(-1) and a pressure dependence of (PCO2PCO0.24)-P-0.76. The second one has an apparent acitvation energy of 100.6 kJ mol(-1) and a pressure dependence of (PCO2PCO0.73)-P-0.27. Based on the experimental results, we give the kenetic expression for the CO2 electroreduction rate on CMO. |
| WOS关键词 | IMPEDANCE SPECTRA ; OXIDE ; CONVERSION ; CEO2 ; DECONVOLUTION ; ACTIVATION ; REDUCTION ; OXIDATION ; CATALYSTS ; CARBON |
| 资助项目 | National Science Foundation of China[91534128] ; National Science Foundation of China[21506208] ; National Science Foundation of China[21476230] ; Ministry of Science and Technology of China[2016YFE0118300] ; DNL Cooperation Fund, CAS[DNL180306] |
| WOS研究方向 | Electrochemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000463752300006 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Science Foundation of China ; National Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; National Science Foundation of China ; National Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; National Science Foundation of China ; National Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; National Science Foundation of China ; National Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/165608]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Cheng, Mojie |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Div Fuel Cells, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Weishen,Cheng, Mojie,Huang, Zhidong,et al. Charge Transfer Reactions in CO2 Electroreduction on Manganese Doped Ceria[J]. CHEMELECTROCHEM,2019,6(6):1668-1672. |
| APA | Yang, Weishen.,Cheng, Mojie.,Huang, Zhidong.,Shang, Lei.,Qi, Huiying.,...&Tu, Baofeng.(2019).Charge Transfer Reactions in CO2 Electroreduction on Manganese Doped Ceria.CHEMELECTROCHEM,6(6),1668-1672. |
| MLA | Yang, Weishen,et al."Charge Transfer Reactions in CO2 Electroreduction on Manganese Doped Ceria".CHEMELECTROCHEM 6.6(2019):1668-1672. |
入库方式： OAI收割
来源：大连化学物理研究所
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