Conversion of MeOH and Toluene into Styrene and Ethylbenzene Using Composite Catalysts Containing MeOH Dehydrogenation Components
文献类型：期刊论文
| 作者 | Han, Qiao1,2,3,4; Li, Peidong1,2,3,4; Zhang, Yanfei1,2,3,4; Lu, Peng3; Xu, Li3; Guo, Hongchen1,4; Xu, Lei3 |
| 刊名 | CHEMCATCHEM
 |
| 出版日期 | 2019-03-20 |
| 卷号 | 11期号:6页码:1610-1614 |
| 关键词 | dehydrogenation side-chain alkylation coupling reaction composite catalysts heterogeneous catalysis |
| ISSN号 | 1867-3880 |
| DOI | 10.1002/cctc.201801648 |
| 通讯作者 | Xu, Lei(leixu@dicp.ac.cn) |
| 英文摘要 | A new strategy, the coupling of methanol dehydrogenation and side-chain alkylation of toluene, to realize highly effective conversion of methanol and toluene into styrene and ethylbenzene was proposed. A series of composite catalysts were designed by combining CsX with numerous catalysts reported to be effective for methanol dehydrogenation to formaldehyde. The studies of side-chain alkylation of toluene with methanol over these composite catalysts indicated that the introduction of methanol dehydrogenation components could universally improve the yield of styrene and ethylbenzene in side-chain alkylation of toluene with methanol. And the introduction of some methanol dehydrogenation components, i.e. sodium borate (Na2B4O7) and CuO/SiO2, could even double the yield of styrene and ethylbenzene. Furthermore, the influence of the mass ratio of different components and the spatial arrangement of different active sites on composite catalysts was investigated in detail. |
| WOS关键词 | SIDE-CHAIN ALKYLATION ; SELECTIVE CONVERSION ; LOWER OLEFINS ; METHANOL ; FORMALDEHYDE ; ZEOLITE ; SYNGAS ; CESIUM ; BORON ; OXIDE |
| 资助项目 | National Natural Science Foundation of China[21506202] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000463960000008 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/165638]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Xu, Lei |
| 作者单位 | 1.Dalian Univ Technol, Dept Catalyt Chem & Engn, Dalian 116012, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Lab Clean Energy, Dalian 116023, Peoples R China 4.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han, Qiao,Li, Peidong,Zhang, Yanfei,et al. Conversion of MeOH and Toluene into Styrene and Ethylbenzene Using Composite Catalysts Containing MeOH Dehydrogenation Components[J]. CHEMCATCHEM,2019,11(6):1610-1614. |
| APA | Han, Qiao.,Li, Peidong.,Zhang, Yanfei.,Lu, Peng.,Xu, Li.,...&Xu, Lei.(2019).Conversion of MeOH and Toluene into Styrene and Ethylbenzene Using Composite Catalysts Containing MeOH Dehydrogenation Components.CHEMCATCHEM,11(6),1610-1614. |
| MLA | Han, Qiao,et al."Conversion of MeOH and Toluene into Styrene and Ethylbenzene Using Composite Catalysts Containing MeOH Dehydrogenation Components".CHEMCATCHEM 11.6(2019):1610-1614. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。