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Oxygen Evolution Reaction over the Au/YSZ Interface at High Temperature

文献类型：期刊论文

作者Song, Yuefeng2,3; Zhou, Si4; Dong, Qiao1,3; Li, Yangsheng2,3; Zhang, Xiaomin2; Ta, Na2; Liu, Zhi1; Zhao, Jijun4; Yang, Fan2; Wang, Guoxiong2
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
出版日期2019-03-26
卷号58期号:14页码:4617-4621
ISSN号1433-7851
关键词electrolysis metal-oxide interfaces oxygen evolution reaction solid oxide electrolysis cells
DOI10.1002/anie.201814612
通讯作者Wang, Guoxiong(wanggx@dicp.ac.cn) ; Bao, Xinhe(xhbao@dicp.ac.cn)
英文摘要The oxygen evolution reaction (OER) is a sluggish electrocatalytic reaction in solid oxide electrolysis cells (SOECs) at high temperatures (600-850 degrees C). Perovskite oxide has been widely investigated for catalyzing the OER; however, the formation of cation-enriched secondary phases at the oxide/oxide interface blocks the active sites and decreases OER performance. Herein, we show that the Au/yttria-stabilized zirconia (YSZ) interface possesses much higher OER activity than the lanthanum strontium manganite/YSZ anode. Electrochemical characterization and density functional theory calculations suggest that the Au/YSZ interface provides a favorable path for OER by triggering interfacial oxygen spillover from the YSZ to the Au surface. In situ X-ray photoelectron spectroscopy results confirm the existence of spillover oxygen on the Au surface. This study demonstrates that the Au/YSZ interface possesses excellent catalytic activity for OER at high temperatures in SOECs.
WOS关键词OXIDE ELECTROCHEMICAL-CELLS ; CO2 ELECTROLYSIS ; NEXT-GENERATION ; NANOPARTICLES ; CATHODE ; CERIA ; PEROVSKITE ; STABILITY ; METHANOL ; STATE
资助项目National Key R&D Program of China[2017YFA0700102] ; National Natural Science Foundation of China[21573222] ; National Natural Science Foundation of China[91545202] ; Dalian National Laboratory for Clean Energy[DNL180404] ; Dalian Institute of Chemical Physics[DICP DMT0201702] ; Dalian Outstanding Young Scientist Foundation[2017R.103] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XD131.7020200] ; CAS Youth innovation Promotion[2015145]
WOS研究方向Chemistry
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000462622700028
资助机构National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian National Laboratory for Clean Energy ; Dalian National Laboratory for Clean Energy ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; Dalian Outstanding Young Scientist Foundation ; Dalian Outstanding Young Scientist Foundation ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; CAS Youth innovation Promotion ; CAS Youth innovation Promotion ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian National Laboratory for Clean Energy ; Dalian National Laboratory for Clean Energy ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; Dalian Outstanding Young Scientist Foundation ; Dalian Outstanding Young Scientist Foundation ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; CAS Youth innovation Promotion ; CAS Youth innovation Promotion ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian National Laboratory for Clean Energy ; Dalian National Laboratory for Clean Energy ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; Dalian Outstanding Young Scientist Foundation ; Dalian Outstanding Young Scientist Foundation ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; CAS Youth innovation Promotion ; CAS Youth innovation Promotion ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian National Laboratory for Clean Energy ; Dalian National Laboratory for Clean Energy ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; Dalian Outstanding Young Scientist Foundation ; Dalian Outstanding Young Scientist Foundation ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; CAS Youth innovation Promotion ; CAS Youth innovation Promotion
源URL[http://cas-ir.dicp.ac.cn/handle/321008/165696]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Wang, Guoxiong; Bao, Xinhe
作者单位1.Chinese Acad Sci, State Key Lab Funct Mat Informat, Shanghai Inst Microsyst & Informat Technol, Shanghai 200050, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis,Ctr Excellence Nanosci, Zhongshan Rd 457, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
4.Dalian Univ Technol, Key Lab Mat Modificat Laser Ions & Electron Beams, Minist Educ, Dalian 116024, Peoples R China
推荐引用方式
GB/T 7714		 Song, Yuefeng,Zhou, Si,Dong, Qiao,et al. Oxygen Evolution Reaction over the Au/YSZ Interface at High Temperature[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(14):4617-4621.
APA Song, Yuefeng.,Zhou, Si.,Dong, Qiao.,Li, Yangsheng.,Zhang, Xiaomin.,...&Bao, Xinhe.(2019).Oxygen Evolution Reaction over the Au/YSZ Interface at High Temperature.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(14),4617-4621.
MLA Song, Yuefeng,et al."Oxygen Evolution Reaction over the Au/YSZ Interface at High Temperature".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.14(2019):4617-4621.

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来源：大连化学物理研究所

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