Crystal structure, magnetic and heat capacity properties of a new chiral mononuclear iron(II) compound
文献类型：期刊论文
| 作者 | Zheng, Hui; Liu, Xin; Yin, Nan; Tan, Zhicheng; Shi, Quan |
| 刊名 | JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
 |
| 出版日期 | 2019-03-01 |
| 卷号 | 135期号:6页码:3421-3428 |
| 关键词 | Chiral mononuclear complex Magnetic property Heat capacity Thermodynamic function PPMS |
| ISSN号 | 1388-6150 |
| DOI | 10.1007/s10973-018-7619-7 |
| 通讯作者 | Shi, Quan(shiquan@dicp.ac.cn) |
| 英文摘要 | A new chiral mononuclear iron(II) compound, formulated as {[Fe(ACBP)(3)]center dot(ClO4)} (1, ACBP = (S,S)-3,3'-(1,2-dimethylpropanedioxy)-2,2'-bipyridine), has been synthesized and structurally characterized. The magnetic study revealed that compound 1 possesses antiferromagnetic exchange interactions between Fe(II) ions through the hydrogen bonds. The low-temperature heat capacity of compound 1 was measured in the temperature range from 1.9 to 300 K using the heat capacity option of a Quantum Design Physical Property Measurement System (PPMS). Additionally, the thermodynamic functions in the experimental temperature range have been derived by fitting the heat capacity data to a series of theoretical and empirical models. The standard molar heat capacity, entropy and enthalpy of compound 1 at 298.15 K and 0.1 MPa have been determined to be = (1036.9 +/- 10.4) J mol(-1) K-1, = (1059.6 +/- 10.6) J mol(-1) K-1 and = (160.29 +/- 1.60) kJ mol(-1), respectively. |
| WOS关键词 | THERMODYNAMIC FUNCTIONS ; COMPLEXES ; LIGANDS |
| 资助项目 | Natural Science Foundation of China[21473198] ; Natural Science Foundation of China[21701167] |
| WOS研究方向 | Thermodynamics ; Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000462553400049 |
| 出版者 | SPRINGER |
| 资助机构 | Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/165720]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Shi, Quan |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Liaoning Prov Key Lab Thermochem Energy & Mat, Thermochem Lab,Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Hui,Liu, Xin,Yin, Nan,et al. Crystal structure, magnetic and heat capacity properties of a new chiral mononuclear iron(II) compound[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2019,135(6):3421-3428. |
| APA | Zheng, Hui,Liu, Xin,Yin, Nan,Tan, Zhicheng,&Shi, Quan.(2019).Crystal structure, magnetic and heat capacity properties of a new chiral mononuclear iron(II) compound.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,135(6),3421-3428. |
| MLA | Zheng, Hui,et al."Crystal structure, magnetic and heat capacity properties of a new chiral mononuclear iron(II) compound".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 135.6(2019):3421-3428. |
入库方式： OAI收割
来源：大连化学物理研究所
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